417556
4-Fluorophenylboronic acid
≥95%
Synonym(s):
(4-Fluorophenyl)boric acid, (4-Fluorophenyl)dihydroxyborane, (4-Fluorophenyl)dihydroxyboron, (p-Fluorophenyl)boric acid, 4-Fluorobenzeneboronic acid, p-Fluorobenzylboronic acid, p-Fluorophenylboronic acid, NSC 142683
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About This Item
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Assay
≥95%
form
powder
mp
262-265 °C (lit.)
functional group
fluoro
SMILES string
OB(O)c1ccc(F)cc1
InChI
1S/C6H6BFO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
InChI key
LBUNNMJLXWQQBY-UHFFFAOYSA-N
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Application
It can also be used as a reactant in:
- Suzuki coupling using microwave and triton B catalyst.[4]
- Pd-catalyzed direct arylation of pyrazoles with phenylboronic acids.[5]
- Mizoroki-Heck and Suzuki-Miyaura coupling reactions catalyzed by palladium nanoparticles.[6]
- Cu-catalyzed Petasis reactions.[7]
- Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence.[8]
- Ruthenium catalyzed direct arylation.[9]
- Rh-catalyzed asymmetric conjugate additions.[10]
- Ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids.[11]
- Regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions.[12]
- Suzuki cross-coupling of tetrabromothiophene.[13]
- Palladium-catalyzed addition to nitriles.[14]
Other Notes
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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