376876
N-Methoxy-N-methyl(triphenylphosphoranylidene)acetamide
98%
Synonym(s):
(N-Methoxymethylaminocarbonylmethylene)triphenylphosphorane
About This Item
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Assay
98%
reaction suitability
reaction type: C-C Bond Formation
mp
173-175 °C (lit.)
functional group
amine
phosphine
SMILES string
CON(C)C(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C22H22NO2P/c1-23(25-2)22(24)18-26(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21/h3-18H,1-2H3
InChI key
DGBLSOOPDBHHRX-UHFFFAOYSA-N
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Application
- Synthesis of electron-deficient alkenes via stereoselective olefination of N-sulfonyl imines
- Phosphine-catalyzed asymmetric addition reactions
- Cysteine-catalyzed enantioselective intramolecular Rauhut-Currier reaction
- Wittig olefination
- Synthesis of aigialomycin D, a Protein Kinase inhibitor and a potential anticancer agent
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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