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vapor density
3 (vs air)
vapor pressure
155 mmHg ( 21.1 °C)
Assay
≥99%
form
liquid
autoignition temp.
487 °F
refractive index
n20/D 1.388 (lit.)
bp
60-66 °C (lit.)
density
0.678 g/mL at 25 °C (lit.)
functional group
allyl
SMILES string
CCCCC=C
InChI
1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3
InChI key
LIKMAJRDDDTEIG-UHFFFAOYSA-N
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General description
The kinetics of polymerization of 1-hexene was studied using a family of five zirconium amine bis-phenolate catalysts. Polymerization reaction of 1-hexene catalyzed by a series of hafnium complexes was studied.
Application
- 1-Hexene in High Molecular Weight Polymer Synthesis: The synthesis of high molecular weight copolymers from 1-hexene and methyl acrylate using Lewis acid catalysts showcased advanced applications in materials science, specifically in developing durable and versatile polymer materials (Wan et al., 2024).
- 1-Hexene′s Role in Proton-Exchange Membrane Enhancement: Utilizing 1-hexene in the structural characterization and enhancement of physicochemical properties of functionally porous proton-exchange membranes highlights its critical role in improving energy efficiency and performance in fuel cell technologies (Ponomar et al., 2024).
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 2
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point(F)
-13.0 °F - closed cup
Flash Point(C)
-25.0 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Journal of the American Chemical Society, 135(16), 6280-6288 (2013-03-23)
The kinetics of 1-hexene polymerization using a family of five zirconium amine bis-phenolate catalysts, Zr[tBu-ON(X)O]Bn2 (where X = THF (1), pyridine (2), NMe2 (3), furan (4), and SMe (5)), has been investigated to uncover the mechanistic effect of varying the
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Non-bridged half-metallocene dimethyl complexes of group 4 metals 2a-4a with an N-4-methoxyphenyl(iminomethyl)pyrrolyl ligand 1a were synthesized and characterized by NMR spectroscopy and X-ray analysis. Upon activation with [Ph3C][B(C6F5)4], these complexes became active catalysts for the polymerization of 1-hexene. A series
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The stereochemistry, kinetics, and mechanism of olefin polymerization catalyzed by a set of zirconium-based metallocenes was studied by NMR using dissolution dynamic nuclear polarization (DNP). Hyperpolarized 1-hexene was polymerized in situ with a C2 symmetric catalyst, [(EBI)ZrMe][B(C6F5)4] (EBI = rac-(C2H4(1-indenyl)2))
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