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229407

Sigma-Aldrich

Aluminum isopropoxide

≥99.99% trace metals basis

Synonym(s):

AIP, Aluminum isopropylate, Aluminum triisopropoxide

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About This Item

Linear Formula:
Al[OCH(CH3)2]3
CAS Number:
Molecular Weight:
204.24
Beilstein:
3910275
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

≥99.99% trace metals basis

form

powder and chunks
solid

reaction suitability

core: aluminum
reagent type: catalyst

mp

128-133 °C (lit.)

density

1.035 g/mL at 25 °C (lit.)

SMILES string

CC(C)O[Al](OC(C)C)OC(C)C

InChI

1S/3C3H7O.Al/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3

InChI key

SMZOGRDCAXLAAR-UHFFFAOYSA-N

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General description

Aluminum isopropoxideis a metal-organic compound that consists of an aluminum atom bonded with threeisopropoxide ligands. It is used as a precursor for the synthesis of high-surfacearea alumina and other aluminum-containing materials. In addition, it is usedto prepare metalorganic chemical precursors for the growth of thinfilms and coatings.

Application

Aluminum isopropoxide can be used as:
  • Sol-gel precursor to synthesize ZnAl2O4 powders for transparent ceramics.
  • Precursor material for the fabrication of nanosized SAPO-34 zeolites with a 4-fold increase in catalytic lifetime and significantly increased selectivity.
  • A starting material to prepare long-persistent luminescence materials for display devices and bioimaging.
  • Coating material to fabricate electrodes for lithium-ion batteries to enhance cycling stability and performance.
  • A catalyst for alkylation of resorcinol with camphene.

Pictograms

Flame

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Flam. Sol. 1

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 1

Flash Point(F)

60.8 °F - closed cup

Flash Point(C)

16 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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F Javier Benitez et al.
Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering, 40(12), 2153-2169 (2005-12-02)
Acetovanillone [Ethanone, 1-(4-hydroxy-3-metoxyphenyl)] is one of the major pollutants that is present in the wastewater produced during the boiling of raw material in the cork industry. The oxidation of its aqueous solutions by monochromatic UV radiation alone and combined with
Sol-gel synthesis and characterization of ZnAl2O4 powders for transparent ceramics
A.V.Belyaev, et al.
Ceramics International, 45, 4835-4839 (2019)
Chandradass, J.; et al.
Materials Science & Engineering. A, Structural Materials : Properties, Microstructure and Processing, 408 (1-2), 165-168 (2005)
SrAl2O4: Eu2+, Dy3+ phosphors derived from a new sol?gel route
Yiqing Lu, et al.},
Microelectronics Journal, 35, 379-382 (2004)
Chandradass, J.; et al.
Journal of Materials Processing Technology, 173 (3), 275-280 (2006)

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