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204854

Sigma-Aldrich

Vanadium(V) oxide

greener alternative

99.9% trace metals basis

Synonym(s):

Divanadium pentaoxide, Divanadium pentoxide, Pentaoxodivanadium, Vandia

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About This Item

Linear Formula:
V2O5
CAS Number:
Molecular Weight:
181.88
EC Number:
MDL number:
UNSPSC Code:
12352303
eCl@ss:
38180404
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99.9% trace metals basis

form

powder

composition

V2O5

reaction suitability

reagent type: catalyst
core: vanadium

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

690 °C (lit.)

density

3.35 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

greener alternative category

SMILES string

O=[V](=O)O[V](=O)=O

InChI

1S/5O.2V

InChI key

GNTDGMZSJNCJKK-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more details.

Application

Selective ammoxidation catalysts for such reactions as conversion of toluene to benzonitrile or propylene to acrylonitrile were prepared by a sol-gel method from V2O5, Sb2O3 and high purity hydrogen peroxide. Preparation of new stabilized, oxide ion-conducting, bismuth vanadate phases by a microwave assisted method, fromV2O5, Bi2O3 and other solid oxides, was reported. These ceramics show promise in solid oxide fuel cells, water-vapor electrolyzers and oxygen sensors.

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 1B - Lact. - Muta. 2 - Repr. 2 - STOT RE 1 Inhalation - STOT SE 3

Target Organs

Respiratory system, Respiratory Tract

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Gongming Wang et al.
ACS nano, 6(11), 10296-10302 (2012-10-12)
Here we report a new strategy to improve the electrochemical stability of vanadium oxide electrodes for pseudocapacitors. Vanadium oxides are known to suffer from severe capacitance loss during charging/discharging cycling, due to chemical dissolution and ion intercalation/deintercalation-induced material pulverization. We
Yeon Seok Kim et al.
Applied biochemistry and biotechnology, 168(5), 1143-1152 (2012-09-06)
The bactericidal activity of TiO(2) nanoparticles under visible light is very important in regards to its practical applications. In this paper, we synthesized vanadium-pentoxide-loaded TiO(2) nanoparticles (V(2)O(5)-TiO(2)) using a chemical vapor condensation method, followed by the impregnation method, and characterized
Junkal Gutierrez et al.
ChemSusChem, 5(12), 2323-2327 (2012-10-13)
A bacterial cellulose mat was used as a template for the fabrication of conductive photoswitchable hybrid nanopaper by the incorporation of sol-gel synthesized vanadium nanoparticles. The resulting nanopaper, prepared through a green pathway, was able to photoinduce a reversible color
Hongchang Pang et al.
Chemical communications (Cambridge, England), 49(15), 1536-1538 (2013-01-17)
A template-free strategy is exploited to bottom-up synthesize yolk-shell vanadium oxide through a two-step spontaneous assembly of hydrolytically formed subunits in a one-pot process. The unique structured vanadium pentoxide exhibits excellent cathode performance for lithium ion batteries.
M Gruber et al.
The Journal of chemical physics, 138(9), 094704-094704 (2013-03-15)
Extended cluster models together with density-functional theory are used to evaluate geometric, energetic, and electronic properties of different adsorbate species that can occur at a vanadium oxide surface where the selective catalytic reduction (SCR) of NO in the presence of

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