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177199

Sigma-Aldrich

Methyl propargyl ether

≥97%

Synonym(s):

3-Methoxy-1-propyne, Methyl 2-propynyl ether

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About This Item

Linear Formula:
HC≡CCH2OCH3
CAS Number:
627-41-8
Molecular Weight:
70.09
Beilstein:
878166
EC Number:
210-998-1
MDL number:
MFCD00008578
UNSPSC Code:
12352100
PubChem Substance ID:
24850621
NACRES:
NA.22

Assay

≥97%

form

liquid

refractive index

n20/D 1.396 (lit.)

bp

61-62 °C (lit.)

density

0.83 g/mL at 25 °C (lit.)

functional group

ether

storage temp.

2-8°C

SMILES string

COCC#C

InChI

1S/C4H6O/c1-3-4-5-2/h1H,4H2,2H3

InChI key

YACFFSVYSPMSGS-UHFFFAOYSA-N

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General description

The Raman spectra of methyl propargyl ether has been studied.

Application

Methyl propargyl ether was used in the synthesis of [Ru3(μ3-κ(2)-HNNMe2)(μ3-κ(2)-MeOCH2CCH2)(μ-CO)2(CO)6].

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Statements

H225,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-0.4 °F - closed cup

Flash Point(C)

-18 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Javier A Cabeza et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(20), 6040-6052 (2005-07-30)
The reactions of the hydrido-triruthenium cluster complex [Ru3(mu-H)(mu3-kappa(2)-HNNMe2)(CO)9] (1; H2NNMe2 = 1,1-dimethylhydrazine) with alkynes that have alpha-hydrogen atoms give trinuclear derivatives containing edge-bridging allyl or face-capping alkenyl ligands. Under mild conditions (THF, 70 degrees C) the isolated products are as
Conformational stability, barriers to internal rotation, ab initio calculations and vibrational assignment of methyl propargyl ether.
Journal of Molecular Structure, 320, 193-216 (1994)

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