146048

2-Adamantanone

ReagentPlus^®, 99%

• Synonym(s): 2-Oxoadamantane, Tricyclo[3.3.1.13,7]decanone (9CI)
• Empirical Formula (Hill Notation): C₁₀H₁₄O
• CAS Number: 700-58-3
• Molecular Weight: 150.22
• Beilstein: 1210235
• EC Number: 211-847-2
• MDL number: MFCD00074737
• UNSPSC Code: 12352100
• PubChem Substance ID: 24848757
• NACRES: NA.22

Properties

• Quality Level: 100
• product line: ReagentPlus^®
• Assay: 99%
• form: solid
• mp: 256-258 °C (subl.) (lit.)
• functional group: ketone
• SMILES string: O=C1C2CC3CC(C2)CC1C3
• InChI: 1S/C10H14O/c11-10-8-2-6-1-7(4-8)5-9(10)3-6/h6-9H,1-5H2/t6-,7+,8-,9+
• InChI key: IYKFYARMMIESOX-SPJNRGJMSA-N

Description

General description

2-Adamantanone on deprotonation in the gas phase affords the corresponding β-enolate anion. It reacts with 1,1-dilithio-1-sila-2,3,4,5-tetraphenylsilole to yield 5-silafulvene.

Application

2-Adamantanone was used in the synthesis of dispiro N-Boc-protected 1,2,4-trioxane and (+/-)-1-(adamantan-2-yl)-2-propanamine.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 2
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves