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Sigma-Aldrich

PEDOT:PSS

greener alternative

high-conductivity grade, 1.5% aqueous dispersion, neutral pH

Synonym(s):

Orgacon™ N-1005, PEDOT:PSS, Poly(2,3-dihydrothieno-1,4-dioxin)-poly(styrenesulfonate)

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About This Item

MDL number:
MFCD07371079
UNSPSC Code:
12352103
NACRES:
NA.23
Pricing and availability is not currently available.

Product Name

Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate), 1.5% in H2O, high-conductivity grade, neutral pH

form

liquid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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concentration

1.5% in H2O

resistance

<100 Ω/sq, >70% visible light transmission (40 μm wet)

refractive index

n20/D 1.335

pH

5-7

viscosity

<100 cP(22 °C)

density

0.982 g/mL at 25 °C

greener alternative category

Enabling,

storage temp.

2-8°C

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General description

Aqueous surfactant-free dispersion of PEDOT:PSS neutralized to pH >5. Suitable for preparation of pH-neutral transparent conductive films printed electronics applications (e.g. hole injection layers). A conducting polymer such as poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonate) anions (PEDOT/PSS) is widely used in various organic optoelectronic devices.[1][2][3] PEDOT: PSS is a blend of cationic polythiopene derivative, doped with a polyanion. High electrical conductivity and good oxidation resistance of such polymers make it suitable for electromagnetic shielding and noise suppression. Thus, the polymer film was found to possess high transparency throughout the visible light spectrum and even into near IR and near UV regions, virtually 100% absorption from 900-2,000 nm. No absorption maximum from 400-800 nm. Impact of small electric and magnetic fields on the polymer was studied. [4]
Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) is a conductive polymer that is formed by electropolymerizing 3,4-ethylenedioxythiophene in a solution of poly(styrenesulfonate) (PSS). PEDOT is doped with positive ions and PSS with negative ions. PEDOT:PSS is majorly used in organic electronics due to the properties such as:[5][6]
  • low band gap
  • good optical properties
  • high conductivity
  • low redox potential
  • easy processing
  • tunable film forming ability

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This product is used in energy conversion and storage, thus has been enhanced for energy efficiency. Click here for more information.

Application

PEDOT:PSS can be used as an electrode material that forms a layered structure with a high mobility for charge carriers. It can be used for a wide range of energy based applications, such as organic photovoltaics (OPVs), dye sensitized solar cells (DSSCs), organic light emitting diodes (OLEDs) and supercapacitors.[7][8][9][10][11]
Virtually 100% absorption from 900-2,000 nm. No absorption maximum from 400-800 nm. Conductive polymer blend.

Legal Information

Product of Agfa
Orgacon is a trademark of Agfa-Gevaert N.V.

Pictograms

Health hazardCorrosion
GHS08,GHS05

Signal Word

Danger

Hazard Statements

H315,H318,H360D

Hazard Classifications

Eye Dam. 1 - Repr. 1B - Skin Irrit. 2

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB0721
STBL1717
STBK6683
STBK4654
STBK2232

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Optimizing polymer tandem solar cells.
Jan Gilot et al.
Advanced materials (Deerfield Beach, Fla.), 22(8), E67-E71 (2010-03-11)
Materials for Energy Harvesting and Storage
Zardetto V, et al.
Material Matters, 9(4), 771-5765 (2014)
Bolognesi M, et al.
Organic Photonics and Photovoltaics, 1(4), 1-10 (2013)
Roll-to-Roll Slot-Die Coated Organic Photovoltaic (OPV) Modules with High Geometrical Fill Factors
Galagan Y, et al.
Energy Technology, 3(8), 834-842 (2015)
Screen-printable and flexible RuO2 nanoparticle-decorated PEDOT: PSS/graphene nanocomposite with enhanced electrical and electrochemical performances for high-capacity supercapacitor.
Cho S, et al.
ACS Applied Materials & Interfaces, 7(19), 10213-10227 (2015)
View All Related Papers

Articles

Conducting Polymer Materials for Flexible OPV Applications: Orgacon™ PEDOT : PSS

A detailed article on conducting polymer materials for flexible organic photovoltaics (OPVs) applications.

New Conducting and Semiconducting Polymers for Plastic Electronics

In the field of organic printable electronics, such as OLEDs and organic photovoltaics (OPVs), improved organic conducting and semiconducting materials are needed. The progress in two fields is reviewed in this article.

New Conducting and Semiconducting Polymers for Plastic Electronics

In the field of organic printable electronics, such as OLEDs and organic photovoltaics (OPVs), improved organic conducting and semiconducting materials are needed. The progress in two fields is reviewed in this article.

New Conducting and Semiconducting Polymers for Plastic Electronics

In the field of organic printable electronics, such as OLEDs and organic photovoltaics (OPVs), improved organic conducting and semiconducting materials are needed. The progress in two fields is reviewed in this article.

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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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