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449857

Sigma-Aldrich

Lanthanum(III) fluoride

anhydrous, powder, 99.99% trace metals basis

Synonym(s):

Lanthanum fluoride, Lanthanum trifluoride

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About This Item

Linear Formula:
LaF3
CAS Number:
Molecular Weight:
195.90
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

grade

anhydrous

Quality Level

Assay

99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: lanthanum

impurities

≤200.0 ppm Trace Rare Earth Analysis

density

5.936 g/mL at 25 °C (lit.)

SMILES string

F[La](F)F

InChI

1S/3FH.La/h3*1H;/q;;;+3/p-3

InChI key

BYMUNNMMXKDFEZ-UHFFFAOYSA-K

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Application

Employed extensively in the preparation and study of fluoride glasses.

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Bingdi Chen et al.
Journal of colloid and interface science, 367(1), 61-66 (2011-10-19)
Multifunctional magnetic-fluorescent nanohybrids were successfully fabricated by a facile layer-by-layer (LBL) self-assembly of in situ generated Eu, Gd co-doped LaF(3) nanocrystals (LaF(3):Eu:Gd) on the surface of multi-walled carbon nanotubes (MWNTs). Photoluminescence (PL) quenching occurred when LaF(3):Eu:Gd nanoparticles were directly coated
Song Ye et al.
Optics express, 16(12), 8989-8994 (2008-06-12)
Tm(3+)-Yb(3+) codoped transparent oxyfluoride glass ceramics containing LaF(3) nanocrystals were obtained by thermal treatment on the as-made glasses. The formation of LaF(3) nanocrystals and the incorporation of Tm(3+) and Yb(3+) into LaF(3) nanocrystal lattice were confirmed by X-ray diffraction and
Ibrahim H A Badr et al.
Journal of the American Chemical Society, 127(15), 5318-5319 (2005-04-14)
A highly selective, sensitive, and reversible fluoride optical sensing film based on aluminum(III)octaethylporphyrin as a fluoride ionophore and a lipophilic pH indicator as the optical transducer is described. The fluoride optical sensing films exhibit a submicromolar detection limit and high
Peter R Diamente et al.
Langmuir : the ACS journal of surfaces and colloids, 22(4), 1782-1788 (2006-02-08)
The binding of Eu3+-doped LaF3 nanoparticles with biotin moieties at the surface of the stabilizing ligand layer to avidin, immobilized on cross-linked aragose beads, is described. The biotin moieties were attached to the nanoparticles by reaction of an activated ester
Jian-Xin Meng et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 66(1), 81-85 (2006-07-04)
LaF3:Eu3+ nanoparticles were prepared by a simple hydrothermal process at low temperature and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and fluorescence spectrum. Well-dispersed nanoparticles with an average size of 30 nm and a hexagonal shape were obtained.

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Rare earth elements are vital in everyday life worldwide: catalysts in cars, colors in screens, magnets in electronics. Essential for modern living.

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