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Sigma-Aldrich

Poly(tetrahydrofuran)

average Mn ~1,000

Synonym(s):

α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), polyTHF

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About This Item

Linear Formula:
H(OCH2CH2CH2CH2)nOH
CAS Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
Pricing and availability is not currently available.

vapor pressure

<0.01 mmHg ( 25 °C)
<1 mmHg ( 20 °C)

mol wt

average Mn ~1,000

contains

0.05-0.07% BHT as stabilizer

mp

25-33 °C

density

0.974 g/mL at 25 °C

SMILES string

OCCCCO

InChI

1S/C8H18O2/c1-3-5-6-10-8(4-2)7-9/h8-9H,3-7H2,1-2H3/t8-/m0/s1

InChI key

BJZYYSAMLOBSDY-QMMMGPOBSA-N

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Application

Poly(tetrahydrofuran) can be used as a starting material to prepare:
  • Thermally reversible urethane -epoxy networks.
  • Poly(hexamethylene 2,6-naphthalate)-block-poly(tetrahydrofuran) (PHN-b-N-pTHF) copolymers with shape memory effect via melt polycondensation.
  • Poly(3,4-ethylenedioxythiophene):poly(tetrahydrofuran) composite for the fabrication of memory organic electrochemical transistors.

Features and Benefits

  • High flexibility
  • Hydrolytic stability
  • Excellent abrasion resistance

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

>325.4 °F - Tag open cup

Flash Point(C)

> 163 °C - Tag open cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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W K Loke et al.
Biomaterials, 17(22), 2163-2172 (1996-11-01)
Hybrid biomaterials have been produced by the interaction of polyurethane oligomers with both fresh and glutaraldehyde-fixed porcine pericardium. The hybrid biomaterials so formed were translucent with occasional white streaks and/or spots, had increased stiffness (to touch) but remained pliable. No
Antony Memboeuf et al.
Journal of the American Society for Mass Spectrometry, 22(10), 1744-1752 (2011-09-29)
Collision induced dissociation tandem mass spectrometry experiments were performed to unequivocally separate compounds from an isobaric mixture of two products. The Survival Yield curve was obtained and is shown to consist in a linear combination of the curves corresponding to
A Takahara et al.
Journal of biomaterials science. Polymer edition, 5(3), 183-196 (1993-01-01)
The relationships among surface, bulk properties and lipid sorption behaviors of segmented polyurethanes (SPUs) with various polyol soft segments were investigated. The polyols used in this study were poly(ethylene oxide) (PEO), poly(tetramethylene oxide) (PTMO), and poly(dimethylsiloxane) (PDMS). The hard segment
A Brandwood et al.
Journal of biomaterials science. Polymer edition, 6(1), 41-54 (1994-01-01)
A series of novel polyurethane elastomers based on methylenediphenyl diisocyanate, 1,4-butanediol and the macrodiols, poly(hexamethylene oxide), poly(octamethylene oxide), and poly(decamethylene oxide) were implanted subcutaneously in sheep for periods of 3 and 6 months. The specimens that were subjected to 3
R Nakaoka et al.
Journal of biomedical materials research, 49(1), 99-105 (1999-11-24)
Interaction of macrophages (Mos) with polyetherurethane (PEU) was investigated to clarify the role of the Mos in the early stage of tumorigenesis of PEUs. As for the inflammatory cytokines produced from Mos, the amount of tumor necrosis factor (TNF) produced

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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