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B46808

Sigma-Aldrich

Bis(2-hydroxyphenyl)methane

98%

Synonym(s):

2,2′-Methylenediphenol

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About This Item

Linear Formula:
CH2(C6H4OH)2
CAS Number:
2467-02-9
Molecular Weight:
200.23
EC Number:
219-578-2
MDL number:
MFCD00002243
UNSPSC Code:
12352100
PubChem Substance ID:
24891800
NACRES:
NA.22

Assay

98%

form

powder

mp

113-118 °C (lit.)

SMILES string

Oc1ccccc1Cc2ccccc2O

InChI

1S/C13H12O2/c14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)15/h1-8,14-15H,9H2

InChI key

MQCPOLNSJCWPGT-UHFFFAOYSA-N

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Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Occupational allergic contact dermatitis from epoxy resins based on bisphenol F.
A Pontén et al.
Contact dermatitis, 41(4), 235-235 (1999-10-09)
M Bruze
Contact dermatitis, 14(4), 228-232 (1986-04-01)
The sensitizing capacity of 2,2(1)-dihydroxydiphenyl methane (2,2(1)-HPM), 4,4(1)-dihydroxydiphenyl methane (4,4(1)-HPM) and 2,4(1)-dihydroxydiphenyl methane (2,4(1)-HPM) was investigated with the guinea pig maximization test. These compounds are known contact sensitizers in phenol-formaldehyde resins. The study was performed to assess and compare their
Nathan R Pillsbury et al.
The journal of physical chemistry. A, 113(17), 5000-5012 (2009-04-08)
Laser-induced fluorescence, single-vibronic level fluorescence (SVLF), UV hole burning, and fluorescence dip infrared (FDIR) spectroscopy have been carried out on bis-(2-hydroxyphenyl)methane in order to characterize the ground-state and first excited-state vibronic spectroscopy of this model flexible bichromophore. These studies identified
Nathan R Pillsbury et al.
The journal of physical chemistry. A, 113(17), 5013-5021 (2009-04-08)
Stimulated emission pumping-population transfer spectroscopy (SEP-PTS) has been used to directly measure the energy threshold to isomerization between the two conformational isomers of bis(2-hydroxyphenyl)methane. These conformers have been shown in the preceding paper (DOI 10.1021/jp8098686) to be an OH...O H-bonded
M Bruze et al.
Dermatosen in Beruf und Umwelt. Occupation and environment, 33(6), 216-220 (1985-01-01)
16 patients with contact allergy to phenol-formaldehyde resins (P-F-R) were patch tested with 3 dihydroxydiphenyl methanes (bisphenol F). The chemical investigation by high pressure liquid chromatography indicated that the dihydroxydiphenyl methanes (HPM) were pure and separable. 9 patients reacted to
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