34072
2,4-Dibromobutyryl chloride
technical, ~90% (GC)
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About This Item
Linear Formula:
BrCH2CH2CHBrCOCl
CAS Number:
Molecular Weight:
264.34
Beilstein:
4955401
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
grade
technical
Assay
~90% (GC)
refractive index
n20/D 1.535
density
2.00 g/mL at 20 °C
storage temp.
2-8°C
SMILES string
ClC(=O)C(Br)CCBr
InChI
1S/C4H5Br2ClO/c5-2-1-3(6)4(7)8/h3H,1-2H2
InChI key
WYZLYWUZERABRL-UHFFFAOYSA-N
Application
2,4-Dibromobutyryl chloride was used in the preparation of:
- methyl 2,4-dibromobutanoate
- series of 3-(3, 5-di-tert-butyl-4-hydroxybenzylidene)pyrrolidin-2-ones, anti-inflammatory/analgesic agents
- α-bromolactam
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
Supplementary Hazards
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Preparation of enantiopure 2-acylazetidines and their reactions with chloroformates.
Ma S, et al.
Tetrahedron Letters, 48(2), 269-271 (2007)
H Ikuta et al.
Journal of medicinal chemistry, 30(11), 1995-1998 (1987-11-01)
A series of 3-(3,5-di-tert-butyl-4-hydroxybenzylidene)pyrrolidin-2-ones was synthesized and evaluated as candidate antiinflammatory/analgesic agents as well as dual inhibitors of prostaglandin and leukotriene synthesis. Some compounds that showed dual inhibitory activity were found to possess equipotent antiinflammatory activities to indomethacin, with reduced
Bhooma Raghavan et al.
The Journal of organic chemistry, 71(5), 2151-2154 (2006-02-25)
A concise, stereoselective synthesis of alpha-substituted gamma-lactams is reported. gamma-Lactam scaffolds 2 and 3, possessing an Evans' chiral auxiliary and two types of N substituents, were successfully alkylated with different electrophiles to give alpha-substituted gamma-lactams with reasonable diastereoselectivities. The use
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