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920991

Sigma-Aldrich

Silver(I) carbonate

≥99.9% trace metals basis

Synonym(s):

Silver carbonate

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About This Item

Linear Formula:
Ag2CO3
CAS Number:
534-16-7
Molecular Weight:
275.75
Beilstein:
6936654
MDL number:
MFCD00003403
UNSPSC Code:
12352302
NACRES:
NA.23

Quality Level

200

Assay

≥99.9% trace metals basis

form

powder

mp

210 °C (dec.) (lit.)

density

6.08 g/mL at 25 °C (lit.)

SMILES string

[Ag]OC(=O)O[Ag]

InChI

1S/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

KQTXIZHBFFWWFW-UHFFFAOYSA-L

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Application

Silver carbonate can be used as a catalyst to synthesize α-trifluoromethylacrylic acids and 2-(pyridin-3-yl)pyrimidines (PPMDs), key building blocks for synthesizing bioactive molecules. Additionally, Ag2CO3 can also be used to functionalize metallofullerenes with potential photovoltaic and biomedical applications.

Pictograms

CorrosionEnvironment
GHS05,GHS09

Signal Word

Danger

Hazard Statements

H318,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCP8260
MKCT9457
MKCS5909

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Ligand Free Palladium-Catalyzed Synthesis of a-Trifluoromethylacrylic Acids and Related Acrylates by Three-Component Reaction
Xiao P, et al.
Advanced Synthesis & Catalysis, 362(4), 949-954 (2020)
Jia Li et al.
Frontiers in chemistry, 8, 593602-593602 (2020-11-17)
A novel radical reaction of monometallofullerene Y@C2v(9)-C82 with N-arylbezamidine (1) is successfully conducted through catalysis with silver carbonate. The high-performance liquid chromatographic and mass spectrum results demonstrate that the reaction is highly regioselective to afford only one monoadduct (2) with
Silver-catalyzed cascade reactions of 3-cyanochromone with 1, 1-enediamines: synthesis of highly functionalized 2-(pyridin-3-yl)-chromeno [2, 3-d] pyrimidines.
Xiao Q, et al.
Organic Chemistry Frontiers : An International Journal of Organic Chemistry / Royal Society of Chemistry, 7(15), 2035-2039 (2020)

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