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CRM06796

Supelco

Chloridazon

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Synonym(s):

Pyrazone

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About This Item

Empirical Formula (Hill Notation):
C10H8ClN3O
CAS Number:
Molecular Weight:
221.64
Beilstein:
397241
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material
TraceCERT®

Quality Level

product line

TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

storage temp.

−20°C

SMILES string

NC1=C(Cl)C(=O)N(N=C1)c2ccccc2

InChI

1S/C10H8ClN3O/c11-9-8(12)6-13-14(10(9)15)7-4-2-1-3-5-7/h1-6H,12H2

InChI key

WYKYKTKDBLFHCY-UHFFFAOYSA-N

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ. Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate. Download your certificate at: http://www.sigma-aldrich.com.

Chloridazon is a selective organochlorine herbicide that belongs to the group of pyridazinone compounds. It acts as systemic soil and leaf herbicide by inhibiting the photosynthesis process. It is used for pre-plant, pre-emergence, and early post-emergence, to control annual broad-leaved weeds, sugar beets, and red table beets.

Chloridazon is not authorized for use in the European Union as per the European Council Directive 91/414/EEC concerning the placement of plant protection products on the European market. Maximum residue levels (MRLs) have been set according to Reg (EU) 2016/1015 for Chloridazon for various products of plant and animal origin from 0.05 to 5 mg/kg.

Application

Chloridazon may be used as certified reference material for the following:
  • To examine the effects of chloridazon on the response of the frog neuroepithelial synapse to electrical stimulation and the basal values of the bioelectric parameters of the frog skin
  • To study the transformation of n-chloridazon in a fixed bed bioreactor for verification of microbial degradability at different dosed contamination levels and govern the adaptation processes
  • To investigate the effects of thermal and acid treatments on the sorption properties of a natural sepiolite by evaluating the adsorption process of chloridazon herbicide
  • To prepare and characterize controlled release formulations of chloridazon using biodegradable polymers like ethylcellulose and lignin
  • To investigate the potential use of lignin-based controlled release formulations (CRFs) to control release rate and leaching of metribuzin and chloridazon in soils
  • To synthesize a meso-sorbent silica/polyaniline (MSNPs/PANI) composite for the removal of the chloridazon pesticide from the aqueous solution

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Gianluigi Buttiglieri et al.
Water research, 43(11), 2865-2873 (2009-04-30)
A sampling campaign was carried out for n-chloridazon (n-CLZ) and its degradation product desphenyl-chloridazon (DPC) in the Hesse region (Germany) during the year 2007: a total of 548 environmental samples including groundwater, surface water and wastewater treatment plant (WWTP) effluent
F Flores-Céspedes et al.
Journal of hazardous materials, 343, 227-234 (2017-09-30)
In this research, controlled release formulations (CRFs) of the herbicides chloridazon and metribuzin, identified as potential leachers, have been evaluated in soils with different texture. To prepare the CRFs, ethylcellulose (EC) and dibutylsebacate (DBS) have been used as coating agents
Review of the existing maximum residue levels for chloridazon according to Article 12 of Regulation (EC) No 396/2005
European Food Safety Authority
EFSA Journal, 4226 null
E González-Pradas et al.
Water research, 39(9), 1849-1857 (2005-05-19)
The adsorption of chloridazon on heat treated sepiolite samples at 110 degrees C (S-110), 200 degrees C (S-200), 400 degrees C (S-400), 600 degrees C (S-600) and acid treated samples with H2SO4 solutions of two different concentrations (0.25 and 1.0M)
M Suwalsky et al.
Comparative biochemistry and physiology. Part C, Pharmacology, toxicology & endocrinology, 120(1), 29-35 (1998-11-25)
Chloridazon is a widely used organochlorine herbicide. In order to evaluate its perturbing effect on cell membranes it was made to interact with human erythrocytes, frog adrenergic neuroepithelial synapse and molecular models. These consisted in multilayers of dimyristoylphosphatidylethanolamine (DMPE) and

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