Skip to Content
Merck
All Photos(1)

Key Documents

8.08270

Sigma-Aldrich

Triphenylphosphine

for synthesis

Synonym(s):

Triphenylphosphine, Phosphorus triphenyl

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
(C6H5)3P
CAS Number:
Molecular Weight:
262.29
MDL number:
UNSPSC Code:
12352128
EC Index Number:
210-036-0
NACRES:
NA.22
Pricing and availability is not currently available.

vapor pressure

0.0000012 hPa ( 20 °C)

Quality Level

Assay

≥99.0% (GC)

form

solid

autoignition temp.

425 °C

potency

700 mg/kg LD50, oral (Rat)
>4000 mg/kg LD50, skin (Rabbit)

reaction suitability

reagent type: reductant

bp

377 °C/1013 hPa

mp

78.5-81.5 °C

transition temp

flash point 182 °C

solubility

<0.0001 g/L

density

1.194 g/cm3 at 20 °C

bulk density

500‑600 kg/m3

storage temp.

2-30°C

SMILES string

P(c3ccccc3)(c2ccccc2)c1ccccc1

InChI

1S/C18H15P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

InChI key

RIOQSEWOXXDEQQ-UHFFFAOYSA-N

Analysis Note

Assay (GC, area%): ≥ 99.0 % (a/a)
Melting range (lower value): ≥ 79 °C
Melting range (upper value): ≤ 82 °C
Identity (IR): passes test

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1B - STOT RE 1 Inhalation

Storage Class Code

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

Flash Point(F)

356.0 °F - closed cup

Flash Point(C)

180 °C - closed cup


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service