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S5012

Sigma-Aldrich

Sodium hypophosphite monohydrate

≥99%

Synonym(s):

Sodium hypophosphite 1-hydrate, Sodiumphosphinite

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About This Item

Linear Formula:
NaH2PO2 · H2O
CAS Number:
10039-56-2
Molecular Weight:
105.99
EC Number:
231-669-9
MDL number:
MFCD06252379
UNSPSC Code:
12352302
PubChem Substance ID:
57654620
NACRES:
NA.22

Assay

≥99%

form

powder, crystals or chunks

solubility

water: 100 mg/mL, clear, colorless

SMILES string

O.[Na+].[O-][PH2]=O

InChI

1S/Na.H3O2P.H2O/c;1-3-2;/h;3H2,(H,1,2);1H2/q+1;;/p-1

InChI key

PLZNPHDJGFDNRM-UHFFFAOYSA-M

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Application

Sodium hypophosphite monohydrate can be used as a:
  • Reducing agent in the synthesis of nickel nanoparticles (NiNP) from nickel acetate tetrahydrate under microwave irradiation.
  • Hydrogen donor in the enantioselective transfer hydrogenation of aliphatic and aromatic ketones to corresponding alcohols in presence of ruthenium catalyst.
  • Catalyst in esterification of spent grain to improve heavy metal ions adsorption capacity using N,N-dimethylformamide (DMF) as a solvent.

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Microwave assisted greener synthesis of nickel nanoparticles using sodium hypophosphite.
Eluri R and Paul B
Materials Letters, 76, 36-39 (2012)
Fast esterification of spent grain for enhanced heavy metal ions adsorption.
Li Q, et al.
Bioresource Technology, 101(10), 3796-3799 (2010)
Biphasic Glycerol/2-MeTHF, Ruthenium-Catalysed Enantioselective Transfer Hydrogenation of Ketones Using Sodium Hypophosphite as Hydrogen Donor.
Guyon C, et al.
European Journal of Organic Chemistry, 2013(24), 5439-5444 (2013)
Lukas J Goossen et al.
Chemical communications (Cambridge, England), (8)(8), 836-837 (2002-07-19)
A catalyst generated in situ from palladium acetate and tricyclohexylphosphine efficiently catalyzes the reduction of carboxylic acids with sodium hypophosphite in the presence of pivalic anhydride to give aldehydes with high selectivity. The low cost and convenient handling of the
R Wadhwa et al.
Gerontology, 35(1), 14-18 (1989-01-01)
Addition of antioxidant, sodium hypophosphite (SHP; 1 mM), to the diet of Zaprionus paravittiger (Diptera) results in depressed ATPase activity in both the sexes in comparison to the normal group. However, the rate of age-related decline in ATPase activity is
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