If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
922900
GPhos Pd G6 TES
Synonym(s):
GPhos OAC precatalyst TES
About This Item
Recommended Products
form
powder
Quality Level
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
SMILES string
[Pd]([PH](C5CCCCC5)(C4CCCCC4)c2c(ccc(c2c3c(cccc3C(C)C)C(C)C)C)C)(Br)c1ccc(cc1)C(=O)OCC[Si](C)(C)C
InChI
1S/C32H47P.C12H17O2Si.BrH.Pd/c1-22(2)28-18-13-19-29(23(3)4)31(28)30-24(5)20-21-25(6)32(30)33(26-14-9-7-10-15-26)27-16-11-8-12-17-27;1-15(2,3)10-9-14-12(13)11-7-5-4-6-8-11;;/h13,18-23,26-27H,7-12,14-17H2,1-6H3;5-8H,9-10H2,1-3H3;1H;
InChI key
TZDQPFRWRQKAKO-UHFFFAOYSA-N
Application
Learn more about G6 Buchwald precatalysts
related product
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Articles
Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.
Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.
Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.
Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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What does the abbreviation "TES" stand for in the names of tBuBrettPhos Pd G6 TES (912883) and GPhos Pd G6 TES (922900)?
1 answer-
For products 912883 and 922900, "TES" refers to the Trimethylethylsilyl (TMSCH2CH2) group.
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