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715301

Sigma-Aldrich

Manganese bis(trifluoromethanesulfonate)

Synonym(s):

Manganese triflate, Manganese trifluoromethanesulfonate

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About This Item

Empirical Formula (Hill Notation):
C2F6MnO6S2
CAS Number:
55120-76-8
Molecular Weight:
353.08
MDL number:
MFCD17015267
UNSPSC Code:
12161600
PubChem Substance ID:
329762961
NACRES:
NA.22

form

solid

reaction suitability

core: manganese
reagent type: catalyst

impurities

5% metallic Mn

mp

>400 °C

SMILES string

FC(F)(F)S(=O)(=O)O[Mn]OS(=O)(=O)C(F)(F)F

InChI

1S/2CHF3O3S.Mn/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

InChI key

HEYNLDRKZOOEDN-UHFFFAOYSA-L

General description

Manganese bis(trifluoromethanesulfonate) is also known as manganese triflate. It is used as a catalyst in organic synthesis for the oxidation of various hydrocarbons, epoxidation, and C-H oxidation reactions.

Application

Catalyst for:
  • Biginelli reactions
  • Methanolysis

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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