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01302

Fluosilicic acid

purum, 33.5-35%

Synonym(s):

Fluorosilicic acid, Hexafluorosilicic acid, Hydrogen hexafluorosilicate

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About This Item

Linear Formula:
H2SiF6
CAS Number:
Molecular Weight:
144.09
UNSPSC Code:
12352300
eCl@ss:
38130308
PubChem Substance ID:
NACRES:
NA.21
MDL number:
Concentration:
33.5-35%
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grade

purum

Quality Level

concentration

33.5-35%

impurities

≤0.003% heavy metals (as Pb)

density

1.22 g/mL at 20 °C (lit.), 1.31 g/mL at 25 °C

anion traces

chloride (Cl-): ≤0.2%, phosphate (PO43-): ≤1000 mg/kg, sulfate (SO42-): ≤0.2%

cation traces

Fe: ≤100 mg/kg

SMILES string

F.F.F[Si](F)(F)F

InChI

1S/F4Si.2FH/c1-5(2,3)4;;/h;2*1H

InChI key

ZEFWRWWINDLIIV-UHFFFAOYSA-N

General description

High-silic fluoro silicic acids have been prepared. They have desired amount of extra silica upto 18% more than the composition as represented by H2SiF6. Preparation and properties of fluosilicic acid have been reported. Fluosilicic acid can be obtained as a major byproduct of phosphate fertilizer industry.It can be used in the preparation of sodium fluorosilicate, via neutralization with sodium chloride. It can also undergo neutralization with ammonia to produce ammonium fluoride and silica.

Application

Fluosilicic acid (FSA, H2SiF6) has been used in the following studies:
  • Fluoridation of fluoridated municipal water supplies.[1]
  • Surface modification of calcium carbonate.
  • Liquid phase deposition (LPD) of silica.[2]

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This Item
3727571.003121.00314
grade

purum

grade

-

grade

-

grade

-

concentration

33.5-35%

concentration

20-25 wt. % in H2O

concentration

25%

concentration

37%

Quality Level

200

Quality Level

-

Quality Level

500

Quality Level

500

cation traces

Fe: ≤100 mg/kg

cation traces

-

cation traces

-

cation traces

-

density

1.22 g/mL at 20 °C (lit.), 1.31 g/mL at 25 °C

density

1.22 g/mL at 25 °C

density

1.12 g/cm3 at 20 °C, 1.18 g/mL at 20 °C

density

1.18 g/mL at 20 °C, 1.19 g/cm3 at 20 °C

anion traces

phosphate (PO43-): ≤1000 mg/kg, chloride (Cl-): ≤0.2%, sulfate (SO42-): ≤0.2%

anion traces

-

anion traces

-

anion traces

-


pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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"Recovery of high surface area mesoporous silica from waste hexafluorosilicic acid (H 2 SiF 6) of fertilizer industry"
Sarawade.BP, et al.
Journal of Hazardous Materials, 173(01), 576-580 (2010)
Fluosilicic acid.
Journal of Chemical Education, 35(11), 562-562 (1958)
Elizabeth A Whitsitt et al.
Journal of colloid and interface science, 287(1), 318-325 (2005-05-26)
Liquid phase deposition (LPD) of silica from soluble silicates has been performed in the presence of dodecyltrimethylammonium bromide (DTAB), sodium dodecyl sulfate (SDS) and sodium dodecylbenzyl sulfate (SDBS). The morphology of the silica varies between semi-ordered uniform spheres to low



Global Trade Item Number

SKUGTIN
01302-6X1L04061838608925
01302-1L04061838608918

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