All Photos(1)
About This Item
Empirical Formula (Hill Notation):
C13H23ClN2Ni
CAS Number:
Molecular Weight:
301.48
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
95%
form
powder
reaction suitability
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
SMILES string
CC1=CC=CC=C1[Ni]Cl.CN(C)CCN(C)C
InChI
1S/C7H7.C6H16N2.ClH.Ni/c1-7-5-3-2-4-6-7;1-7(2)5-6-8(3)4;;/h2-5H,1H3;5-6H2,1-4H3;1H;/q;;;+1/p-1
InChI key
NMLMESVZRUMFAE-UHFFFAOYSA-M
Related Categories
Application
Effective precatalyst for a variety of nickel-catalyzed transformations, including Suzuki-Miyaura, Buchwald-Hartwig and other cyclizations and oxidative couplings.
related product
Product No.
Description
Pricing
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Jason D Shields et al.
Organic letters, 17(9), 2166-2169 (2015-04-18)
The synthesis and catalytic activity of [(TMEDA)Ni(o-tolyl)Cl], an air-stable, crystalline solid, is described. This complex is an effective precatalyst in a variety of nickel-catalyzed transformations. The lability of TMEDA allows a wide variety of ligands to be used, including mono-
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