425117
Ethyl 2-butynoate
98%
Synonym(s):
Ethyl tetrolate
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About This Item
Linear Formula:
CH3C≡CC(O)OCH2CH3
CAS Number:
Molecular Weight:
112.13
Beilstein:
1744948
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
98%
form
liquid
refractive index
n20/D 1.436 (lit.)
bp
160-161 °C/730 mmHg (lit.)
density
0.962 g/mL at 25 °C (lit.)
functional group
ester
SMILES string
CCOC(=O)C#CC
InChI
1S/C6H8O2/c1-3-5-6(7)8-4-2/h4H2,1-2H3
InChI key
FCJJZKCJURDYNF-UHFFFAOYSA-N
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General description
Ethyl 2-butynoate, a 2-alkynoate is a methanogenesis inhibitor. It is an electron deficient internal alkyne that has been reported to undergo codimerization with alkenes to form 1,3-dienes catalyzed by rhodium(I)/H8-BINAP complex. The annulation of thioamides with ethyl 2-butynoate catalyzed by tri-n-butylphosphine to form thiazolines has been investigated.
Application
Ethyl 2-butynoate was used in the study of its effect on in vitro degradation and microbial biomass production.
It may be used in the synthesis of the following:
It may be used in the synthesis of the following:
- 3-ethyl, 1-methyl 1-(2-nitrophenyl)-cyclopent-3-ene-1,3-dicarboxylate
- tricyclic aziridine derivatives
- alkenylsilanols
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
143.6 °F - closed cup
Flash Point(C)
62 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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A cationic rhodium(I)/H(8)-BINAP complex catalyzes codimerization of alkenes bearing no alpha-hydrogen and electron-deficient internal alkynes, leading to 1,3-dienes in good yields with moderate to excellent regio- and stereoselectivity. The same complex also catalyzes codimerization of an acrylate and phenyl-substituted electron-rich
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