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About This Item
Empirical Formula (Hill Notation):
C9H7NO2
CAS Number:
Molecular Weight:
161.16
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
98%
mp
129-132 °C (lit.)
SMILES string
CN1C(=O)c2ccccc2C1=O
InChI
1S/C9H7NO2/c1-10-8(11)6-4-2-3-5-7(6)9(10)12/h2-5H,1H3
InChI key
ZXLYYQUMYFHCLQ-UHFFFAOYSA-N
General description
Photoreduction of N-methylphthalimide (NMP) with 2,3-dimethyl-2-butene has been studied. The selective electroreduction of N-methylphthalimide to 3-hydroxy-2-methyl-isoindolin-1-one in ionic liquids and phenol as a proton donor under silent and ultrasonic conditions has been reported. Single electron transfer (SET)-induced photochemical reaction of NMP with silyl enol ether has been investigated. Nitration of NMP is reported to afford “exclusively” 3-nitro-derivative.
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Nitration of N-alkylphthalimides.
Williams FJ and Donahue PE.
The Journal of Organic Chemistry, 43(8), 1608-1610 (1978)
Constanza Villagrán et al.
Ultrasonics sonochemistry, 12(6), 423-428 (2005-04-26)
The selective electroreduction N-methylphthalimide to 3-hydroxy-2-methyl-isoindolin-1-one has been performed in ionic liquids using phenol as a proton donor under silent and ultrasonic conditions. A significant increase in the rate of electroreduction is shown using ultrasonic activation and in addition high
Single electron transfer induced photoaddition reactions of silyl enol ether to N-methylphthalimide.
Oh SW, et al.
Bull. Korean Chem. Soc., 28(4), 629-629 (2007)
Photoreduction of N-methylphthalimide with 2, 3-dimethyl-2-butene. Evidence for reaction through an electron transfer generated ion pair.
Mazzocchi PH and Klingler L.
Journal of the American Chemical Society, 106(24), 7567-7572 (1984)
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