226866
Silver(I) fluoride
99%
Synonym(s):
Argentous fluoride, Fluorosilver, Silver monofluoride
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About This Item
Empirical Formula (Hill Notation):
AgF
CAS Number:
Molecular Weight:
126.87
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Assay:
99%
form:
powder
Recommended Products
Quality Level
Assay
99%
form
powder
bp
1159 °C/1 atm (lit.)
mp
≥300 °C (lit.)
density
5.852 g/mL at 25 °C (lit.)
SMILES string
F[Ag]
InChI
1S/Ag.FH/h;1H/q+1;/p-1
InChI key
REYHXKZHIMGNSE-UHFFFAOYSA-M
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Application
Silver(I)fluoride can be used as a reagent:
- To synthesize aliphatic fluorinated products via oxidative C-H fluorination reaction using manganese-based catalysts.
- In fluorinates homocoupling reaction of gem-difluoroalkenes.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Bing Gao et al.
Organic letters, 16(1), 102-105 (2013-12-04)
A novel silver(I)-fluoride-mediated homocoupling reaction of β,β-difluorostyrene derivatives is described. The transformation is initiated via nucleophilic addition of silver(I) fluoride to β,β-difluorostyrenes, which is followed by dimerization of the corresponding benzylsilver intermediates. The reaction shows good substrate scope, functional group
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