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71889

Sigma-Aldrich

Sodium persulfate

BioUltra, ≥99%

Synonym(s):

Sodium peroxodisulfate

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About This Item

Linear Formula:
Na2S2O8
CAS Number:
7775-27-1
Molecular Weight:
238.10
EC Number:
231-892-1
MDL number:
MFCD00003501
UNSPSC Code:
12352302
PubChem Substance ID:
57652372
NACRES:
NA.25

product line

BioUltra

Quality Level

100

Assay

≥99%

form

crystals

impurities

insoluble matter, passes filter test

pH

2.5-4.0 (25 °C, 1 M in H2O)

solubility

H2O: 1 M at 20 °C, clear, colorless

anion traces

chloride (Cl-): ≤50 mg/kg

cation traces

Al: ≤5 mg/kg
As: ≤0.1 mg/kg
Ba: ≤5 mg/kg
Bi: ≤5 mg/kg
Ca: ≤50 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
Li: ≤5 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Mo: ≤5 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Sr: ≤5 mg/kg
Zn: ≤5 mg/kg

absorption

cut-off at 309 nm in H2O at 1 M

SMILES string

[Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O

InChI

1S/2Na.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h;;(H,1,2,3)(H,4,5,6)/q2*+1;/p-2

InChI key

CHQMHPLRPQMAMX-UHFFFAOYSA-L

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Application


  • Structure-dependent degradation of phthalate esters with persulfate oxidation activated by thermal in soil.: Sodium persulfate is used for the thermal activation of persulfate oxidation to degrade phthalate esters in soil, demonstrating its effectiveness in environmental remediation applications (Liu et al., 2024).

  • Fluorescence visualization of CO(2)-responsive phase transfer materials targeting at the heterogeneous interfacial reactions in advanced oxidation of naphthenic acid in wastewater.: This study utilizes sodium persulfate in the advanced oxidation process to degrade naphthenic acid in wastewater, providing a novel approach to wastewater treatment through phase transfer materials (Ren et al., 2024).

  • Optimization of leucomalachite green degradation through electron beam and persulfate oxidation using box-behnken design and life cycle assessment.: Sodium persulfate is employed in conjunction with electron beam irradiation to optimize the degradation of leucomalachite green, highlighting its potential in dye wastewater treatment (Tran et al., 2024).

  • Phototuning of Hyaluronic-Acid-Based Hydrogel Properties to Control Network Formation in Human Vascular Endothelial Cells.: Sodium persulfate is used in the synthesis of hyaluronic-acid-based hydrogels, enabling the phototuning of hydrogel properties to control cellular network formation, which is crucial for tissue engineering and regenerative medicine (Elvitigala et al., 2024).

    • https://doi.org/10.1021/acsami.3c18643

Other Notes

Promotor for polymerization reactions

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Ox. Sol. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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G.B. Broun
Methods in Enzymology, 46, 272-272 (1976)
Chenju Liang et al.
Chemosphere, 70(3), 426-435 (2007-08-19)
In situ chemical oxidation with persulfate anion (S2O82*) is a viable technique for remediation of groundwater contaminants such as trichloroethylene (TCE). An accelerated reaction using S2O82* to destroy TCE can be achieved via chemical activation with ferrous ion to generate
Xiaodan Zhao et al.
Journal of the American Chemical Society, 132(16), 5837-5844 (2010-04-03)
By palladium catalysis, the C-H bond functionalization of O-phenylcarbamates with simple arenes has been achieved using sodium persulfate (Na(2)S(2)O(8)), an inexpensive, easy-to-handle, and environmentally friendly oxidant. This oxidative cross-coupling involves two aromatic C-H bonds undergoing concomitant oxidation to furnish a
Chia-Hsien Yen et al.
Journal of hazardous materials, 186(2-3), 2097-2102 (2011-01-25)
In this study, batch experiments were conducted to evaluate the feasibility of petroleum-hydrocarbon contaminated soil remediation using persulfate oxidation. Various controlling factors including different persulfate and ferrous ion concentrations, different oxidants (persulfate, hydrogen peroxide, and permanganate), and different contaminants (diesel
José Fenoll et al.
Journal of hazardous materials, 244-245, 370-379 (2012-12-29)
The photocatalytic degradation of sixteen substituted phenylurea herbicides (PUHs) in pure water has been studied using zinc oxide (ZnO) and titanium dioxide (TiO(2)) as photocatalyst under artificial light irradiation. Photocatalytic experiments showed that the addition of these chalcogenide oxides in
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