901117
trans-Bis(tricyclopentylphosphine)(2-methylphenyl)nickel(II) chloride
Synonym(s):
trans-(PCyp3)2Ni(o-tolyl)Cl
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About This Item
Empirical Formula (Hill Notation):
C37H61ClNiP2
CAS Number:
Molecular Weight:
661.97
UNSPSC Code:
12352200
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form
powder or solid
reaction suitability
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
mp
156-161 °C
SMILES string
CC1=[C-]C=CC=C1.P(C2CCCC2)(C3CCCC3)C4CCCC4.P(C5CCCC5)(C6CCCC6)C7CCCC7.[Ni+2].[Cl-]
Application
The following Ni complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.
Other Notes
Legal Information
Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.
related product
Product No.
Description
Pricing
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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