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204609

Sigma-Aldrich

Thallium(I) nitrate

99.999% trace metals basis

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About This Item

Linear Formula:
TlNO3
CAS Number:
10102-45-1
Molecular Weight:
266.39
EC Number:
233-273-1
MDL number:
MFCD00011280
UNSPSC Code:
12352302
PubChem Substance ID:
24852281
NACRES:
NA.23

Assay

99.999% trace metals basis

form

solid

reaction suitability

core: thallium

mp

206 °C (lit.)

SMILES string

[Tl+].[O-][N+]([O-])=O

InChI

1S/NO3.Tl/c2-1(3)4;/q-1;+1

InChI key

FYWSTUCDSVYLPV-UHFFFAOYSA-N

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Application

  • Thallium(I) nitrate: Primarily used in the synthesis of other thallium compounds due to its reactivity and solubility. It finds applications in the production of special glasses where thallium improves the refractive index and density of the glass. Caution is advised in its use due to its high toxicity and potential environmental impact (Sigma-Aldrich, CAS 10102-45-1).

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - Ox. Sol. 3 - STOT RE 2

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Vânia M T Carneiro et al.
The Journal of organic chemistry, 75(9), 2877-2882 (2010-04-10)
A diastereoselective route to (+)-bakkenolide A is presented from the readily available optically active Wieland-Miescher ketone. This novel synthesis of this sesquiterpene lactone features the following as key stereoselective transformations: (i) the ring contraction reaction of a octalone mediated by
Cecilia Eliana Hanzel et al.
Toxicology and applied pharmacology, 236(1), 59-70 (2009-04-18)
Thallium (Tl) is a highly toxic metal though yet its mechanisms are poorly understood. Previously, we demonstrated that rat pheochromocytoma (PC12) cells exposure to thallous (Tl(I)) or thallic (Tl(III)) cations leads to mitochondrial damage and reduced cell viability. In the
I A Skul'skiĭ et al.
Zhurnal evoliutsionnoi biokhimii i fiziologii, 24(6), 817-821 (1988-11-01)
Studies have been made of the effect of inhibitors of energy metabolism on maintenance of Na and K concentrations, as well as on accumulation of Rb (as an analogue of K) in single neurones of the mollusc P. corneus. Concentrations
Tl+ increases the permeability of the inner membranes of rat liver mitochondria for monovalent cations.
S M Korotkov et al.
Doklady. Biochemistry and biophysics, 378, 145-149 (2001-11-20)
Sergey M Korotkov
Journal of bioenergetics and biomembranes, 41(3), 277-287 (2009-07-25)
It is known that permeability of the inner mitochondrial membrane is low to most univalent cations (K(+), Na(+), H(+)) but high to Tl(+). Swelling, state 4, state 3, and 2,4-dinitrophenol (DNP)-stimulated respiration as well as the membrane potential (DeltaPsi(mito)) of
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