939390

Cobalt(II) fluoride tetrahydrate

99.9% trace metals basis

• Synonyme(s) : Cobalt difluoride hydrate, Cobaltous fluoride tetrahydrate, Difluorocobalt hydrate
• Formule linéaire : CoF₂ · 4H₂O
• Numéro CAS: 13817-37-3
• Poids moléculaire : 168.99
• Numéro MDL: MFCD00149656

Propriétés

• Type: (High purity Salts)
• Niveau de qualité: 100
• Pureté: 98-102% (complexometric); 99.9% trace metals basis
• Forme: powder or crystals
• Impuretés: ≤1500 ppm (trace metals analysis)
• Couleur: faint red to dark red/pink
• Pf: 200 °C
• Solubilité: water: solubleslightly
• Densité: 2.19 g/mL at 25 °C (lit.)
• Traces d'anions: chloride (Cl^-): ≤20 ppm
• Traces de cations: Al: <20 ppm; Cu: <20 ppm; Fe: <20 ppm; K: <20 ppm; Mg: <20 ppm; Na: <20 ppm; Pb: <20 ppm
• Adéquation: catalyst
• Application(s): (Catalyst)
• Chaîne SMILES: O.O.O.O.F[Co]F
• InChI: 1S/Co.2FH.4H2O/h;2*1H;4*1H2/q+2;;;;;;/p-2
• Clé InChI: MNHUTFNEBYCZAF-UHFFFAOYSA-L

Description

Description générale

Cobalt(II) fluoride tetrahydrate is a reddish crystalline solid with slight solubility in water. It serves as a source of cobalt for oxygen-sensitive applications. Additionally, it is employed as a catalyst biaryl cross-coupling reactions.

Application

Cobalt(II) fluoride tetrahydrate is used as a starting material to synthesize 2-dimensional cobalt-fluoride-oxide as an oxygen evolution electrocatalysts using a rapid thermal annealing (RTA) method. In this process, the cobalt(II) fluoride tetrahydrate is placed in an alumina furnace at 400°C. After annealing for 20 minutes in air, the alumina crucible is removed and allowed to cool naturally to room temperature. The resulting products are then rinsed multiple times in deionized water and ethanol to remove any soluble impurities. Finally, the product is dried thoroughly in a vacuum oven at 60°C to obtain the 2D nanosheets sample. Furthermore, when combined with N-Heterocyclic Carbenes, Cobalt(II) fluoride tetrahydrate has been found to be highly effective as a catalyst for cross-coupling reactions between aryl Grignard reagents and aryl as well as heteroaryl halides. This reaction results in the formation of unsymmetrical biaryls.

Informations sur la sécurité

• Pictogrammes: GHS06,GHS05
• Mention d'avertissement: Danger
• Mentions de danger: H301 + H311 + H331,H314
• Conseils de prudence: P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Classification des risques: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B
• Code de la classe de stockage: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable