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745480

Sigma-Aldrich

Zinc isopropylsulfinate

95%

Synonyme(s) :

Baran Isopropylation Reagent, Baran IPS Reagent, Bis((isopropylsulfinyl)oxy)zinc, IPS

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About This Item

Formule empirique (notation de Hill):
C6H14O4S2Zn
Numéro CAS:
1416821-55-0
Poids moléculaire :
279.69
Numéro MDL:
MFCD24386390
Code UNSPSC :
12352001
ID de substance PubChem :
329764984
Nomenclature NACRES :
NA.22
Le tarif et la disponibilité ne sont pas disponibles actuellement.

Niveau de qualité

100

Essai

95%

Forme

solid

Capacité de réaction

reaction type: Allylation
reaction type: C-C Bond Formation

Pertinence de la réaction

reagent type: catalyst
reaction type: C-H Activation
reagent type: diversification reagent

Pf

161-166 °C

Groupe fonctionnel

sulfinic acid

Chaîne SMILES 

CC(C)S(=O)O[Zn]OS(=O)C(C)C

InChI

1S/2C3H8O2S.Zn/c2*1-3(2)6(4)5;/h2*3H,1-2H3,(H,4,5);/q;;+2/p-2

Clé InChI

PEEMMWYYSHSBTQ-UHFFFAOYSA-L

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Application

Zinc isopropylsulfinate (IPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.[1]


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Liaison

Frequently Asked Questions are available for this Product.

Notes préparatoires

may contain up to 1 mole eq ZnCl2

Autres remarques

Previously sold under product number L511161

Pictogrammes

CorrosionExclamation markEnvironment
GHS05,GHS07,GHS09

Mention d'avertissement

Danger

Mentions de danger

H314,H335,H410

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number
MKCN1076
MKCJ2637
MKCD0333
MKCB0914V
MKBX5822V

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Si vous avez besoin d'une version particulière, vous pouvez rechercher un certificat spécifique par le numéro de lot.

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Rie Poulsen et al.
Trials, 18(1), 578-578 (2017-12-05)
Depression and anxiety are among the largest contributors to the global burden of disease and have negative effects on both the individual and society. Depression and anxiety are very likely to influence the individual's work ability, and up to 40%
Chun You et al.
Biotechnology and bioengineering, 114(8), 1855-1864 (2017-04-15)
Myo-Inositol (vitamin B8) is widely used in the drug, cosmetic, and food & feed industries. Here, we present an in vitro non-fermentative enzymatic pathway that converts starch to inositol in one vessel. This in vitro pathway is comprised of four
Q van Geest et al.
NeuroImage. Clinical, 19, 507-515 (2018-07-10)
To explore the added value of dynamic functional connectivity (dFC) of the default mode network (DMN) during resting-state (RS), during an information processing speed (IPS) task, and the within-subject difference between these conditions, on top of conventional brain measures in
Elisa Zamboni et al.
eLife, 9 (2020-11-11)
Adapting to the environment statistics by reducing brain responses to repetitive sensory information is key for efficient information processing. Yet, the fine-scale computations that support this adaptive processing in the human brain remain largely unknown. Here, we capitalise on the
Christopher A Barwacz et al.
The International journal of oral & maxillofacial implants, 33(5), 1126-1135 (2018-09-20)
To evaluate the influence that three different implant-abutment interface designs had on peri-implant mucosal outcomes as assessed by the pink esthetic score (PES) 3 years after delayed implant placement and immediate provisionalization. Adult subjects (n = 141) requiring replacement of
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