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484385

Sigma-Aldrich

Gold(III) chloride solution

99.99% trace metals basis, 30 wt. % in dilute HCl

Synonyme(s) :

Auric chloride, Gold trichloride

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About This Item

Formule linéaire :
HAuCl4
Numéro CAS:
16903-35-8
Poids moléculaire :
339.79
Numéro MDL:
MFCD00011322
Code UNSPSC :
12352302
ID de substance PubChem :
24871946
Nomenclature NACRES :
NA.23

Niveau de qualité

200

Pureté

99.99% trace metals basis

Forme

liquid

Composition

Au, 17 wt. %

Concentration

30 wt. % in dilute HCl

Impuretés

≤150.0 ppm Trace Metal Analysis

Densité

1.637 g/mL at 25 °C

Chaîne SMILES 

[H][Au](Cl)(Cl)(Cl)Cl

InChI

1S/Au.4ClH/h;4*1H/q+3;;;;/p-3

Clé InChI

VDLSFRRYNGEBEJ-UHFFFAOYSA-K

Description générale

Gold(III) chloride solution, commonly called asauric chloride or auric acid is widely used as a precursor to synthesize goldcomplexes and stable gold nanoparticles. It also finds application in the fieldof catalysis.

Application

Noble-Metal Nanostructures with Controlled Morphologies
Gold(III) chloride solution can be used:
  • As a starting material to prepare thiolate-stabilized gold nanoparticles.
  • As an efficient catalyst for single-pot oxidative functionalization of alkanes and alcohols.
  • As a catalyst for diastereoselective alkylation reactions with chiral benzylic acetates.
Suitable precursormaterial for the synthesis of Gold nanorods by using Seed-Mediated Growth Methodwhich has been used for cancer cell imaging and photothermal therapy.

Mention d'avertissement

Danger

Mentions de danger

H290,H302,H314,H373,H411

Classification des risques

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT RE 2 Oral

Organes cibles

Kidney

Code de la classe de stockage

8B - Non-combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

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Certificats d'analyse (COA)

Lot/Batch Number
MKCW1381
MKCW6414
MKCW1380
MKCW9514
MKCV0193

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Nanoparticle Targeting at Cells.
de la Fuente JM, et al.
Langmuir, 22, 3286-3293 (2006)
Preparation and Growth Mechanism of Gold Nanorods (NRs) Using Seed-Mediated Growth Method
Babak Nikoobakht, et al.
Chemistry of Materials, 15, 1957-1962 (2003)
Gold(III)Chloride-Catalyzed Diastereoselective Alkylation Reactions with Chiral Benzylic Acetates
Philipp Rubenbauer and Thorsten Bach
advanced synthesis and catalysis, 350, 1125-1130 (2008)
Commercial gold(I) and gold(III) compounds supported on carbon materials as greener catalysts for the oxidation of alkanes and alcohols
Sonia A. C. Carabineiro, et al.
ChemCatChem, 10, 1804-1813 (2018)
The Golden Pathway to Thiolate-Stabilized Nanoparticles: Following the Formation of Gold(I) Thiolate from Gold(III) Chloride
Brian M. Barngrover and Christine M. Aikens
Journal of the American Chemical Society, 134, 12590-12595 (2022)
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