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463779

Sigma-Aldrich

Ruthenium(III) chloride hydrate

99.98% trace metals basis

Synonyme(s) :

Trichlororuthenium hydrate, Ruthenium trichloride

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About This Item

Formule linéaire :
RuCl3 · xH2O
Numéro CAS:
14898-67-0
Poids moléculaire :
207.43 (anhydrous basis)
Numéro CE :
233-167-5
Numéro MDL:
MFCD00149844
Code UNSPSC :
12352302
ID de substance PubChem :
24870096
Nomenclature NACRES :
NA.23

Niveau de qualité

100

Pureté

99.98% trace metals basis

Forme

powder and chunks

Pertinence de la réaction

reagent type: catalyst
core: ruthenium

Impuretés

≤250.0 ppm Trace Metal Analysis

Chaîne SMILES 

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

Clé InChI

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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Catégories apparentées

Description générale

Ruthenium(III) chloride hydrate exhibits excellent catalytic activity, attributed to the redox properties of ruthenium suitable for fuel cells and other electrochemical devices. It has ability to facilitate charge transfer and exhibit photoactive behavior.

Application

Ruthenium(III) chloride hydrate can be used:
  • As a precursor to prepare ultralow Ru loaded graphene aerogel that exhibits electrocatalytic performance in the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR).
  • As a dopant to prepare Ru-doped TiO2 electron transport layer for mesoscopic perovskite solar cell by spin-coating technique. This helps to enhance photoconversion efficiency and air stability.
  • To fabricate ultra-uniform Ru nanocluster catalyst via small-molecule self-assembly pyrolysis method. These catalysts exhibit excellent hydrogen evolution activity in Zinc air batteries under all pH conditions.

Autres remarques

soluble form

Pictogrammes

CorrosionExclamation markEnvironment
GHS05,GHS07,GHS09

Mention d'avertissement

Danger

Mentions de danger

H302,H314,H411

Classification des risques

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificats d'analyse (COA)

Lot/Batch Number
0000391758
0000391759
0000383866
0000383865
MKCW4909

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Consulter la Bibliothèque de documents

Fujita, S.-I., et al.
J. Catal., 255, 95-95 (2004)
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
Cho, C.S. et al.
Tetrahedron Letters, 40, 1499-1499 (1999)
Yao Zhang et al.
European journal of medicinal chemistry, 86, 449-455 (2014-09-10)
Ruthenium-based anticancer complexes have become increasingly popular for study over the last two decades. Although ruthenium complexes are currently being investigated in clinical trials, there are still some difficulties with their delivery and associated side effects. Human serum albumin (HSA)-based
Huaiyi Huang et al.
Dalton transactions (Cambridge, England : 2003), 44(35), 15602-15610 (2015-08-08)
Ruthenium complexes have been considered as promising substitutes for cisplatin in cancer chemotherapy. However, novel ruthenium-based therapies are faced with some limitations, such as unimpressive cytotoxicity toward solid tumors. Herein, we designed and synthesized phenyl-substituted terpyridyl ruthenium(ii) complexes ([Ru(tpy)(bpy)Cl](+) (Ru1)
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