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Key Documents

458694

Sigma-Aldrich

(Vinylbenzyl)trimethylammonium chloride

99%

Synonyme(s) :

(ar-Vinylbenzyl)trimethylammonium chloride

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About This Item

Formule linéaire :
H2C=CHC6H4CH2N(CH3)3Cl
Numéro CAS:
Poids moléculaire :
211.73
Numéro Beilstein :
3730835
Numéro CE :
Numéro MDL:
Code UNSPSC :
12162002
ID de substance PubChem :
Nomenclature NACRES :
NA.23

Niveau de qualité

Pureté

99%

Pf

240 °C (dec.) (lit.)

Chaîne SMILES 

[Cl-].C[N+](C)(C)Cc1ccc(C=C)cc1

InChI

1S/C12H18N.ClH/c1-5-11-6-8-12(9-7-11)10-13(2,3)4;/h5-9H,1,10H2,2-4H3;1H/q+1;/p-1

Clé InChI

TVXNKQRAZONMHJ-UHFFFAOYSA-M

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Description générale

(Vinylbenzyl)trimethylammonium chloride is a quaternary ammonium salt commonly used as a monomer in polymerization reactions to produce unique polymers. Its vinylbenzyl group allows for easy radical polymerization and copolymerization, enabling incorporation into different polymer backbones like polyacrylates, polyvinyl acetates, and styrene-based polymers. These resulting polymers possess excellent cationic properties, making them suitable for applications such as water treatment, papermaking, textiles, coatings, flocculants, coagulants, dispersants, binders, adhesives, and modifiers.

Application

(Vinylbenzyl)trimethylammonium chloride (VBTA) can be used as a monomer:
  • To synthesize the poly(AMA-DVB-VBTA) monolith columns, which are used for solid-phase microextraction in analytical chemistry.
  • To prepare an anion exchange membrane for a lignin oxidizing electrolyzer. VBTA provides the anion exchange functionality to the copolymer membrane, which allows for the selective transport of anions across the membrane
It is also used to synthesize poly(VBTMAC) (homopolymer) and block copolymers for biomedical applications. For example, it can be used as a monomer to prepare:
  • Poly[oligo(ethylene glycol) methacrylate]-b-based nanostructures for encapsulating magnetic nanoparticles and DNA.
  • Nano-sized polyelectrolyte complexes.
  • Homo and block copolymers of poly(VBTMAC) for non-viral DNA delivery systems.

Autres remarques

Contains a mixture of 3-vinyl isomers and 4-vinyl isomers

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves


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Chen Zheng et al.
Polymers, 12(3) (2020-04-03)
By using different conductivity of polyaniline as filler, a kind of poly(ionic liquid)/polyaniline composite particles was synthesized to investigate the influence of dielectric polarization rate difference between filler and matrix on the electrorheological response and flow stability of composite-based electrorheological
Poly[oligo(ethylene glycol) methacrylate]-b-poly[(vinyl benzyl trimethylammonium chloride)] Based Multifunctional Hybrid Nanostructures Encapsulating Magnetic Nanoparticles and DNA
Angeliki Chroni, et al.
Polymers, 12 (2020)
Poly(vinyl benzyl trimethylammonium chloride) Homo and Block Copolymers Complexation with DNA
Emi Haladjova, et al.
The Journal of Physical Chemistry B, 120, 2586-2595 (2016)
Nunzio Cennamo et al.
Sensors (Basel, Switzerland), 18(6) (2018-06-08)
A novel Molecularly Imprinted Polymer (MIP) able to bind perfluorinated compounds, combined with a surface plasmon resonance (SPR) optical fiber platform, is presented. The new MIP receptor has been deposited on a D-shaped plastic optical fiber (POF) covered with a
Jeffrey M Ting et al.
Molecules (Basel, Switzerland), 25(11) (2020-06-04)
A series of model polyelectrolyte complex micelles (PCMs) was prepared to investigate the consequences of neutral and zwitterionic chemistries and distinct charged cores on the size and stability of nanocarriers. Using aqueous reversible addition-fragmentation chain transfer (RAFT) polymerization, we synthesized

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