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Key Documents

234893

Sigma-Aldrich

Ethyl methacrylate

contains 15-20 ppm monomethyl ether hydroquinone as inhibitor, 99%

Synonyme(s) :

2-Methyl-2-propenoic acid

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About This Item

Formule linéaire :
CH2=C(CH3)COOC2H5
Numéro CAS:
Poids moléculaire :
114.14
Numéro Beilstein :
471201
Numéro CE :
Numéro MDL:
Code UNSPSC :
12162002
ID de substance PubChem :
Nomenclature NACRES :
NA.25

Densité de vapeur

>3.9 (vs air)

Niveau de qualité

Pression de vapeur

15 mmHg ( 20 °C)

Pureté

99%

Forme

liquid

Température d'inflammation spontanée

771 °F

Contient

15-20 ppm monomethyl ether hydroquinone as inhibitor

Indice de réfraction

n20/D 1.413 (lit.)

Point d'ébullition

118-119 °C (lit.)

Densité

0.917 g/mL at 25 °C (lit.)

Température de stockage

2-8°C

Chaîne SMILES 

CCOC(=O)C(C)=C

InChI

1S/C6H10O2/c1-4-8-6(7)5(2)3/h2,4H2,1,3H3

Clé InChI

SUPCQIBBMFXVTL-UHFFFAOYSA-N

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Description générale

Ethyl methacrylate (EMA) is a monomer commonly used in the field of polymer industries. It is an ester of methacrylic acid and ethanol and is a colorless liquid with a characteristic odor. EMA is widely used in the production of various polymers such as poly(methyl methacrylate) (PMMA), poly(ethyl acrylate) (PEA), and ethylene-EMA (EE). These polymers find their application in various fields, including medical implant devices, packaging, paper coatings, textile coatings, emulsion polymers, and plastics.

Ethyl methacrylate is a readily polymerizable monomer used for certain types of acrylic resins. The monomethyl ether hydroxyl quinone present in it is an inhibitor that prevents polymerization.

Application

Ethyl methacrylate (EMA) can be used as a monomer in the following applications:
  • To synthesize artificial nanosized latexes of poly(styrene-co-methyl methacrylate) or poly(styrene-co-ethyl methacrylate), which are in producing drug-releasing films.
  • In the production of additive-manufactured methacrylate-based resins used in dentistry.
  • In the synthesis of a star-shaped block copolymer electrolyte for all-solid-state lithium batteries.
  • In the synthesis of a copolymer used as a matrix for semiconductor nanoparticles, which is crucial for the formation of a stable matrix for the quantum dots-copolymer composite material used in optoelectronic applications.
It can also be used to prepare copolymers of EMA on waxy maize starch and hydroxypropyl starch, the potential application of these copolymers are as excipients for compressed non-disintegrating matrix tablets. It may be used to study reactions of n-butyl acrylate and EMA with ozone in the gas phase.

Pictogrammes

FlameExclamation mark

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

66.2 °F - closed cup

Point d'éclair (°C)

19 °C - closed cup

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Consulter la Bibliothèque de documents

Reactions of n-butyl acrylate and ethyl methacrylate with ozone in the gas phase, Computational and Theoretical Chemistry
Sun Y, et al.
Computational & Theoretical Chemistry, 1039, 33-39 (2014)
M B Abou-Donia et al.
Journal of toxicology and environmental health. Part A, 59(2), 97-118 (2000-02-01)
Ethyl methacrylate (ethyl 2-methyl-2-propenoate, EMA) has been implicated in the development of neurologic impairment following occupational exposure. The potential of EMA to produce neurotoxicity was investigated in adult male Sprague-Dawley rats in two experiments. In the first experiment, animals were
International journal of toxicology, 21 Suppl 1, 63-79 (2002-06-04)
Ethyl Methacrylate is a methacrylate ester used as a chemical additive in artificial fingernail enhancement products. These products may be applied by trained professionals or be provided directly to consumers with instructions for use. Ethyl Methacrylate readily polymerizes and rapidly
Mengwei Pi et al.
Colloids and surfaces. B, Biointerfaces, 78(2), 193-199 (2010-03-30)
The nanoparticles composed of polystyrene core and poly[2-(diethylamino)ethyl methacrylate] (PDEA) hairy shell were used as colloidal templates for in situ silica mineralization, allowing the well-controlled synthesis of hybrid silica core-shell nanoparticles with raspberry-like morphology and hollow silica nanoparticles by subsequent
Elena Torres et al.
Polymers, 12(8) (2020-08-06)
We aimed to study the distribution of hydroxyapatite (HA) and halloysite nanotubes (HNTs) as fillers and their influence on the hydrophobic character of conventional polymers used in the biomedical field. The hydrophobic polyester poly (ε-caprolactone) (PCL) was blended with its

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