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Sigma-Aldrich

Myristyltrimethylammonium bromide

98% (AT)

Synonym(s):

Tetradecyltrimethylammonium bromide, Trimethyl(tetradecyl)ammonium bromide

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About This Item

Linear Formula:
CH3(CH2)13N(Br)(CH3)3
CAS Number:
Molecular Weight:
336.39
Beilstein:
3633227
EC Number:
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22

description

cationic

Quality Level

Assay

≥97.5% (AT)
98% (AT)

form

crystals

mol wt

micellar avg mol wt 27,000

aggregation number

80

CMC

4-5 mM (20-25°C)

mp

245-250 °C (lit.)

solubility

H2O: 0.1 g/mL, clear

SMILES string

[Br-].CCCCCCCCCCCCCC[N+](C)(C)C

InChI

1S/C17H38N.BrH/c1-5-6-7-8-9-10-11-12-13-14-15-16-17-18(2,3)4;/h5-17H2,1-4H3;1H/q+1;/p-1

InChI key

CXRFDZFCGOPDTD-UHFFFAOYSA-M

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General description

Myristyltrimethylammonium bromide (MTAB) is a quaternary ammonium compound that consists of a long-chain alkyl group and a positively charged quaternary ammonium group. It is commonly used as a cationic surfactant and as a phase transfer catalyst in various chemical reactions.

Application

Myristyltrimethylammonium bromide can be used as a cationic surfactant to:
  • Enhance the biomass harvesting and pigments extraction from the cyanobacterium Synechocystis sp. PCC 6803.
  • Facilitate the formation of mixed micelles with amitriptyline hydrochloride.
It can also be used as a capping agent for platinum nanoparticles (Pt NPs), which enhances their catalytic activity in the CO oxidation reaction.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - STOT RE 2 Oral - STOT SE 3

Target Organs

Gastrointestinal tract, Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Mixed micelle formation between amphiphilic drug amitriptyline hydrochloride and surfactants (conventional and gemini) at 293.15- 308.15 K
Rub MA,
The Journal of Physical Chemistry B, 114(19), 6354-6364 (2010)
The role of organic capping layers of platinum nanoparticles in catalytic activity of CO oxidation
Park JY, et al.
Catalysis Letters, 129, 1-6 (2009)
How myristyltrimethylammonium bromide enhances biomass harvesting and pigments extraction from Synechocystis sp. PCC 6803
Zhou Y, et al.
Water Research, 126, 189-196 (2017)
Cexiong Fu et al.
Journal of chromatography. A, 1216(10), 1901-1907 (2009-02-03)
The usefulness of the micellar selectivity triangle (MST) for prediction and interpretation of separation patterns in micellar electrokinetic chromatography (MEKC) separations is presented. In addition, we demonstrate the capability of controlling selectivity properties of micelles through addition of organic modifiers
A Zarbakhsh et al.
Langmuir : the ACS journal of surfaces and colloids, 25(7), 3953-3956 (2009-08-29)
We report information regarding the structure at the interface between hexadecane and an aqueous solution of trimethyl tetradecyl ammonium bromide (C14TAB) with appropriate deuterium labeling. We also report the role of the headgroup size and the charge on structures at

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