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727490

Sigma-Aldrich

Azidobenzene solution

~0.5 M in tert-butyl methyl ether

Synonym(s):

Phenyl azide solution

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About This Item

Empirical Formula (Hill Notation):
C6H5N3
CAS Number:
622-37-7
Molecular Weight:
119.12
Beilstein:
742248
MDL number:
MFCD00040895
UNSPSC Code:
12352100
PubChem Substance ID:
329764323
NACRES:
NA.22

Assay

≥95.0% (HPLC)

Quality Level

100

form

liquid

concentration

~0.5 M in tert-butyl methyl ether

impurities

≤2.0% water

storage temp.

−20°C

SMILES string

[N-]=[N+]=Nc1ccccc1

InChI

1S/C6H5N3/c7-9-8-6-4-2-1-3-5-6/h1-5H

InChI key

CTRLRINCMYICJO-UHFFFAOYSA-N

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Signal Word

Danger

Hazard Statements

H225,H315,H373

Precautionary Statements

P210 - P302 + P352 - P314

Hazard Classifications

Flam. Liq. 2 - Skin Irrit. 2 - STOT RE 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

39.2 °F

Flash Point(C)

4 °C

Certificates of Analysis (COA)

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Azmi Naqvi et al.
Analytical biochemistry, 327(1), 68-73 (2004-03-23)
We report a rapid and versatile procedure for the preparation of photoreactive polymers and light-induced immobilization of proteins onto such polymers. Photoreactive controlled-pore glass, silica gel, glass slide, and polystyrene microtiter plate are prepared in 40-60s by microwave irradiation of
P Nahar et al.
Analytical biochemistry, 294(2), 148-153 (2001-07-11)
A simple and mild procedure is developed for the preparation of an activated polymer surface, used for immobilization of a protein ligand through a covalent linkage. Activation of the polymer surface is carried out by attaching an active functional group
D Wild
Chemico-biological interactions, 82(1), 123-132 (1992-03-01)
Photolysis of arylazides produces short-lived reactive species, very likely arylnitrenium ions which bind to nucleotides and DNA and produce mutations in Salmonella. The present report shows that arylazides can be photo-activated in mammalian (V79 Chinese hamster) cells and that sister
Mary S Rizk et al.
Biochemistry, 45(2), 543-551 (2006-01-13)
The reactive 1,2-didehydroazepine (cyclic ketenimine) intermediates produced upon photolysis of phenyl azide, 3-hydroxyphenyl azide, 3-methoxyphenyl azide, and 3-nitrophenyl azide in water and in HEPES buffer were studied by laser flash photolysis techniques with UV-vis detection of the transient intermediates. The
Sameer A Al-Bataineh et al.
Langmuir : the ACS journal of surfaces and colloids, 25(13), 7432-7437 (2009-07-01)
N-(3-trimethoxysilylpropyl)-4-azido-2,3,5,6-tetrafluorobenzamide (PFPA-silane) was used as a photoactive cross-linker to immobilize antibacterial furanone molecules on silicon oxide surfaces. This immobilization strategy is useful, especially for substrates and molecules that lack reactive functional groups. To this end, cleaned wafers were initially incubated
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