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CRM44794

Supelco

Phosphamidon

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Synonym(s):

2-Chloro-N,N-diethyl-3-(dimethylphosphono)crotonic amide

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About This Item

Empirical Formula (Hill Notation):
C10H19ClNO5P
CAS Number:
13171-21-6
Molecular Weight:
299.69
Beilstein:
8323501
MDL number:
MFCD00055301
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material
TraceCERT®

Quality Level

300

product line

TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

format

neat

storage temp.

−20°C

SMILES string

CCN(CC)C(=O)\C(Cl)=C(\C)OP(=O)(OC)OC

InChI

1S/C10H19ClNO5P/c1-6-12(7-2)10(13)9(11)8(3)17-18(14,15-4)16-5/h6-7H2,1-5H3/b9-8+

InChI key

RGCLLPNLLBQHPF-CMDGGOBGSA-N

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Phosphamidon is a broad-spectrum systemic organophosphorus pesticide. It is used as an insecticide against sap-feeding insects, rice-stem borers, and rice leaf beetles in crops of sugarcane, citrus fruits, commercial cotton, and nuts.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, phosphamidon is not approved for use in the European Union. But a default maximum residue limit (MRL) of 0.01 mg/kg is applicable for the presence of phosphamidon in products of plant origin, in accordance with Regulation (EC) No. 149/2008.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The phosphamidon CRM may also find following uses:
  • Determination of five organophosphorus pesticides in a medicinal herb sample using QuEChERS along with dispersive liquid-liquid microextraction (DLLME) and stacking followed by micellar electrokinetic chromatography (MEKC)
  • Magnetic solid phase microextraction (MSPE) of five organophosphorus pesticides using graphene based cyanopropyltriethoxysilane as an adsorbent from cow′s milk samples and their subsequent determination by gas chromatography with micro-electron capture detector
  • Investigation of residue levels of highly toxic pesticides in 6554 samples of fruits and vegetables by quadrupole time-of-flight LC/MS
  • Analysis of 4 organophosphorus pesticides by gas chromatography with microelectron capture detector following their extraction using a newly synthesized magnetic hybrid material as a solid phase extraction adsorbent
  • Multi-residue analysis of 44 organophosphorus pesticides by QuEChERS method combined with gas chromatography in Pogostemon cablin samples
  • Detection of organophosphorus pesticides in Chinese cabbage sample by a newly designed positive photoionization-ion mobility spectrometry (PP-IMS) apparatus

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Statements

H300,H311,H341,H410

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Muta. 2

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
BCCJ6593
BCCF0887

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Magnetic graphene-based cyanopropyltriethoxysilane as an adsorbent for simultaneous determination of polar and non-polar organophosphorus pesticides in cow?s milk
Nodeh H R, et al.
Royal Society of Chemistry Advances, 6(30), 24853-24864 (2016)
Trace determination of five organophosphorus pesticides by using QuEChERS coupled with dispersive liquid-liquid microextraction and stacking before micellar electrokinetic chromatography
Wei J, et al.
Analytical Methods : Advancing Methods and Applications, 7(14), 5801-5807 (2015)
Yinhui Yang et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 974, 118-125 (2014-12-03)
In this study, a modified quick, easy, cheap, efficient, rugged and safe (QuEChERS) method coupled with gas chromatography with flame photometric detection (GC-FPD) was developed for the determination of 44 organophosphorous pesticide (OPP) residues in 44 batches of Pogostemon cablin
Hui Li et al.
Ecotoxicology and environmental safety, 221, 112428-112428 (2021-06-20)
This study investigated the levels of highly toxic pesticides (HTPs) in 6554 vegetable and fruit samples from 31 regions of China, along with the associated risk of dietary exposure for the population between 2014 and 2017. 18 HTPs were detected
Photocatalytic degradation of phosphamidon using Ag-doped ZnO nanorods
Korake PV, et al.
Toxicological & Environmental Chemistry, 94(6), 1075-1085 (2012)
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