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Key Documents

D129003

Sigma-Aldrich

1,3,4-Thiadiazole-2,5-dithiol

98%

Synonym(s):

Bismuthiol I, 1,3,4-Thiadiazole-2,5-dithiol, Bismuththiol I

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About This Item

Empirical Formula (Hill Notation):
C2H2N2S3
CAS Number:
Molecular Weight:
150.25
Beilstein:
113444
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

powder

mp

162 °C (dec.) (lit.)

SMILES string

Sc1nnc(S)s1

InChI

1S/C2H2N2S3/c5-1-3-4-2(6)7-1/h(H,3,5)(H,4,6)

InChI key

BIGYLAKFCGVRAN-UHFFFAOYSA-N

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Application

Reagent for the determination of bismuth, copper and lead.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Yingchun Fu et al.
The journal of physical chemistry. B, 113(5), 1332-1340 (2009-01-14)
A novel and high-performance biosensing platform was prepared on the basis of one-pot biochemical preoxidation and electropolymerization of monomer (BPEM) for high-load and high-activity immobilization of enzymes. As representative materials here, 2,5-dimercapto-1,3,4-thiadiazole (DMcT) was used as the monomer, glucose oxidase
Yingchun Fu et al.
Analytical chemistry, 83(17), 6511-6517 (2011-07-26)
We report on the exploitation of metal-organic coordination polymers (MOCPs) as new and efficient matrixes to immobilize enzymes for amperometric biosensing of glucose or phenols. A ligand, 2,5-dimercapto-1,3,4-thiadiazole (DMcT), two metallic salts, NaAuCl(4) and Na(2)PtCl(6), and two enzymes, glucose oxidase
Yi Na Jiang et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 22(8), 1079-1083 (2006-08-10)
2,5-Dimercapto-1,3,4-thiadiazol (DMTD) can bind on the surface of a gold electrode through the strong gold-sulfur interaction. The fabrication and electrochemical characteristics of the DMTD self-assembled monolayer (SAM)-modified gold electrode were investigated. The DMTD SAM electrode exhibited a significantly increased sensitivity.
W F Herblin et al.
Life sciences, 56(15), 1257-1264 (1995-03-03)
A rapid, high capacity assay for the binding of basic fibroblast growth factor has been developed. Rat lung tissue was selected as the optimum source of membranes and 2M sodium chloride used to remove endogenous growth factor. The assay has
Yasuyuki Kiya et al.
Langmuir : the ACS journal of surfaces and colloids, 22(25), 10554-10563 (2006-11-30)
The redox reactions of DMcT at PEDOT-modified glassy carbon electrodes (GCEs) in acetonitrile (AN) have been investigated via cyclic voltammetry (CV) and the electrochemical quartz crystal microbalance (EQCM) in order to elucidate the redox reaction mechanism. A redox couple at

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