407518
Julolidine hydrobromide
97%
Synonym(s):
2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizine hydrobromide
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About This Item
Empirical Formula (Hill Notation):
C12H15N · HBr
CAS Number:
Molecular Weight:
254.17
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
form
powder
mp
239-242 °C (lit.)
SMILES string
Br.C1CN2CCCc3cccc(C1)c23
InChI
1S/C12H15N.BrH/c1-4-10-6-2-8-13-9-3-7-11(5-1)12(10)13;/h1,4-5H,2-3,6-9H2;1H
InChI key
KHWBRFVBPGPEOJ-UHFFFAOYSA-N
General description
Julolidines are effective auxofluors that are employed in laser dyes and biochemical stains. They are known to be one of the strongest electron-releasing groups due to electronic and steric factors.
Application
Julolidine hydrobromide may be used in the synthesis of [4-(2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinolin-9-ylazo)-phenyl]-methanol azodye.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B
Supplementary Hazards
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis of julolidine derivatives.
Kauffman JM, et al.
Organic preparations and procedures international, 33(6), 603-613 (2001)
Synthesis, optical characterization and crystal and molecular X-ray structure of a phenylazojulolidine derivative.
Barbero N, et al.
Dyes and Pigments, 92(3), 1177-1183 (2012)
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