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C3881

Sigma-Aldrich

Calcium chloride dihydrate

ReagentPlus®, ≥99.0%

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About This Item

Empirical Formula (Hill Notation):
CaCl2 · 2H2O
CAS Number:
10035-04-8
Molecular Weight:
147.01
EC Number:
233-140-8
MDL number:
MFCD00149613
UNSPSC Code:
12352300
PubChem Substance ID:
329775048
NACRES:
NA.21

vapor pressure

0.01 hPa ( 20 °C)

product line

ReagentPlus®

Assay

≥99.0%

form

powder

pH

5-8 (25 °C, 147 g/L)

mp

176 °C (dec.) (lit.)

SMILES string

O.O.Cl[Ca]Cl

InChI

1S/Ca.2ClH.2H2O/h;2*1H;2*1H2/q+2;;;;/p-2

InChI key

LLSDKQJKOVVTOJ-UHFFFAOYSA-L

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General description

Calcium chloride dihydrate is an inorganic compound that is commonly used as an environmentally friendly catalyst in organic synthesis. It is also used in asymmetric transformation reactions.

Application

Calcium chloride dihydrate can be used as a catalyst:      
  • In the asymmetric 1,4-addition and [3+2]-cycloaddition reactions in the presence of box-type ligands.      
  • To synthesize hexahydropyrimidine derivatives via a one-pot three-component condensation reaction of ethyl/methyl acetoacetate, aniline, and formaldehyde.

It can also be used as a calcium precursor to synthesize macro/mesoporous dicalcium phosphate monolith (CaHPO4) via the sol-gel method using phosphoric acid (H3PO4), and poly(acrylic acid) (PAA).

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H319

Hazard Classifications

Eye Irrit. 2

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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