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32955

Supelco

4,4′-Diaminodiphenyl sulfide

analytical standard

Synonym(s):

4,4′-Thiodianiline

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About This Item

Linear Formula:
S(C6H4NH2)2
CAS Number:
139-65-1
Molecular Weight:
216.30
Beilstein:
1875513
EC Number:
205-370-9
MDL number:
MFCD00025342
UNSPSC Code:
41116107
PubChem Substance ID:
329754407
NACRES:
NA.24

grade

analytical standard

Quality Level

100

Assay

≥99.0% (GC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

mp

105-107 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

SMILES string

Nc1ccc(Sc2ccc(N)cc2)cc1

InChI

1S/C12H12N2S/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12/h1-8H,13-14H2

InChI key

ICNFHJVPAJKPHW-UHFFFAOYSA-N

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Signal Word

Danger

Hazard Statements

H302,H350,H411

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 1B

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL7107
BCCJ8131
BCCF8589
BCCF2849
BCCD4572

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4,4'-Thiodianiline.
Report on carcinogens : carcinogen profiles, 11, III248-III249 (2004-01-01)
L Pomorski et al.
Neoplasma, 49(4), 247-250 (2002-10-17)
Male Wistar rats were divided into two groups. Rats of group 1 were fed basal powdered diet containing 610 ppm 2,4- diaminoanisole sulfate (DAAS), 46 ppm 4,4'-thiodianiline (TDA) and 200 ppm N,N'-diethylthiourea (DETU) for 52 weeks (DTD treatment). Rats of
4,4'-Thiodianiline.
IARC monographs on the evaluation of the carcinogenic risk of chemicals to humans, 27, 147-154 (1982-04-01)
4,4'-Thiodianiline.
Report on carcinogens : carcinogen profiles, 12, 404-405 (2011-08-25)
R Hasegawa et al.
Carcinogenesis, 12(8), 1515-1518 (1991-08-01)
Three thyroid carcinogens, 2,4-diaminoanisole sulfate (DAAS), N,N'-diethylthiourea (DETU) and 4,4'-thiodianiline (TDA), were simultaneously administered in the diet to male F344 rats at one-third the concentration of the reported TD50 levels (610, 200 and 46 p.p.m. respectively) for 52 weeks. The
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