14350

Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer

purum, ≥98.0% rhodium (Rh) basis

• Synonym(s): 2,5-Norbornadiene-rhodium(I) chloride dimer, Chloro(2,5-norbornadiene)rhodium(I) dimer, Rhodium(I) chloride 2,5-Norbornadiene complex dimer, [Rh(nbd)Cl]₂
• Empirical Formula (Hill Notation): C₁₄H₁₆Cl₂Rh₂
• CAS Number: 12257-42-0
• Molecular Weight: 460.99
• EC Number: 235-510-4
• MDL number: MFCD00198060
• UNSPSC Code: 12352300

Properties

• grade: purum
• Assay: ≥98.0% rhodium (Rh) basis
• storage temp.: 2-8°C
• SMILES string: Cl[Rh].Cl[Rh].[CH]1[CH]C2[CH][CH]C1C2.[CH]3[CH]C4[CH][CH]C3C4
• InChI: 1S/2C7H8.2ClH.2Rh/c2*1-2-7-4-3-6(1)5-7;;;;/h2*1-4,6-7H,5H2;2*1H;;/q;;;;2*+1/p-2/t2*6-,7+;;;;
• InChI key: RXDWVIOULPVOEO-SEGRDSFWSA-L

Description

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Hydrosilylation Catalysts

Other Notes

Rhodium(I) complex used for the preparation of Rh-phosphine complexes [1]; Catalyst used for the [2+2]-cycloreversion of strained cyclobutenes [2][3]