686441

Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)

• Synonym(s): Dicarbonylchloro[(1,2,3,4,5,-η)-1,2,3,4,5-pentaphenylcyclo-2,4-pentadien-1-yl)]ruthenium
• Empirical Formula (Hill Notation): C₃₇H₂₅ClO₂Ru
• CAS Number: 677736-23-1
• Molecular Weight: 638.12
• MDL number: MFCD09265041
• UNSPSC Code: 12352300
• PubChem Substance ID: 329761049
• NACRES: NA.22

Properties

• form: solid
• reaction suitability: core: ruthenium; reagent type: catalyst
• mp: 152-167 °C
• SMILES string: Cl[Ru].[C-]#[O+].[C-]#[O+].c1ccc(cc1)[C]2[C]([C]([C]([C]2c3ccccc3)c4ccccc4)c5ccccc5)c6ccccc6
• InChI: 1S/C35H25.2CO.ClH.Ru/c1-6-16-26(17-7-1)31-32(27-18-8-2-9-19-27)34(29-22-12-4-13-23-29)35(30-24-14-5-15-25-30)33(31)28-20-10-3-11-21-28;2*1-2;;/h1-25H;;;1H;/q;;;;+1/p-1
• InChI key: NGSBLRJKXUHTOC-UHFFFAOYSA-M

Description

Application

Reactant for:

• Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst
• Ligand exchange
• Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds

Catalyst for:

• (S)-Selective dynamic kinetic resolution of secondary alcohols
• Stereoselective synthesis of neonicorinoide pesticide derivatives
• Divergent asymmetric synthesis of 3,5-disubstituted piperidines

Citation

Metal catalyst used in conjunction with enzymes for enantioselective transformations via dynamic kinetic resolution

Legal Information

Product of Kanata Chemical Technologies, Inc.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves