Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

661708

Sigma-Aldrich

(R)-(−)-COP-OAc Catalyst

95%

Synonym(s):

Di-μ-acetatobis[η5-(R)-(pR)-2-(2′-(4′-methylethyl)oxazolinyl)cyclopentadienyl,1-C,3′-N)(η4-tetraphenylcyclobutadiene)cobalt]dipalladium

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C82H72O6N2Co2Pd2
CAS Number:
849592-74-1
Molecular Weight:
1512.17
UNSPSC Code:
12352000
PubChem Substance ID:
24884539

Assay

95%

mp

241-251 °C (dec.)

SMILES string

[Co].[Co].CC(=O)[O+]1[Pd-][O+]([Pd-]1)C(C)=O.CC(C)[C@@H]2COC(=N2)[C]3[CH][CH][CH][CH]3.CC(C)[C@@H]4COC(=N4)[C]5[CH][CH][CH][CH]5.c6ccc(cc6)[C]7[C]([C]([C]7c8ccccc8)c9ccccc9)c%10ccccc%10.c%11ccc(cc%11)[C]%12[C]([C]([C]%12c%13ccccc%13)c%14ccccc%14)c%15ccccc%15

InChI

1S/2C28H20.2C11H14NO.2C2H3O2.2Co.2Pd/c2*1-5-13-21(14-6-1)25-26(22-15-7-2-8-16-22)28(24-19-11-4-12-20-24)27(25)23-17-9-3-10-18-23;2*1-8(2)10-7-13-11(12-10)9-5-3-4-6-9;2*1-2(3)4;;;;/h2*1-20H;2*3-6,8,10H,7H2,1-2H3;2*1H3;;;;/q;;;;2*+1;;;2*-1/t;;2*10-;;;;;;/m..00....../s1

InChI key

WZRJKKZQBPMZCQ-TWWPWAOZSA-N

Application

Catalyst used for the synthesis of chiral allylic ethers.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
75996BKV
25396CP
75996BK
10712KD

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Stefan F Kirsch et al.
Organic letters, 9(5), 911-913 (2007-02-06)
[reaction: see text] The reaction of trichloroacetimidate derivatives of (Z)-2-alken-1-ols with phenol nucleophiles in the presence of the palladium(II) catalyst [COP-OAc]2 provides 3-aryloxy-1-alkenes in high yields and high enantiomeric purity (typically 63-90% yield and 90-97% ee). The reaction is exemplified
Ludovic Decultot et al.
Organic letters, 22(14), 5594-5599 (2020-07-07)
The natural nucleoside (+)-sinefungin, structurally similar to cofactor S-adenosyl-l-methionine, inhibits various SAM-dependent methyltransferases (MTs). Access to sinefungin analogues could serve as the basis for the rational design of small molecule methyltransferase inhibitors. We developed a route to the unnatural C9'

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service