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525111

Sigma-Aldrich

3-Methyl-2-thienylzinc bromide solution

0.5 M in THF

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About This Item

Empirical Formula (Hill Notation):
C5H5BrSZn
CAS Number:
Molecular Weight:
242.45
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

concentration

0.5 M in THF

bp

65 °C

density

0.978 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Cc1ccsc1[Zn]Br

InChI

1S/C5H5S.BrH.Zn/c1-5-2-3-6-4-5;;/h2-3H,1H3;1H;/q;;+1/p-1

InChI key

KNFCPQJOQLKVRD-UHFFFAOYSA-M

Application

3-Methyl-2-thienylzinc bromide can be used as a starting material for the synthesis of thiophene-containing natural products pyridoacridines.[1]

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

1.4 °F - closed cup

Flash Point(C)

-17 °C - closed cup


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Synthesis of pyridoacridines through anionic cascade ring closure
Petersen IN and Kristensen JL
Synthesis, 46(11), 1469-1474 (2014)

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