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Key Documents

460702

Sigma-Aldrich

Titanium(III) chloride tetrahydrofuran complex (1:3)

97%

Synonym(s):

THF-titanium trichloride complex, (3:1), Titanium trichloride tetrahydrofuran complex (1:3), Titanium trichloride tri(THF), Titanium trichloride tris(tetrahydrofuran), Trichlorotris(THF)titanium, Trichlorotris(tetrahydrofuran)titanium

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About This Item

Empirical Formula (Hill Notation):
C12H24Cl3O3Ti
CAS Number:
Molecular Weight:
370.54
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:

Assay

97%

form

solid

reaction suitability

reagent type: catalyst
core: titanium

mp

>250 °C (lit.)

storage temp.

2-8°C

SMILES string

Cl[Ti](Cl)Cl.C1CCOC1.C2CCOC2.C3CCOC3

InChI

1S/3C4H8O.3ClH.Ti/c3*1-2-4-5-3-1;;;;/h3*1-4H2;3*1H;/q;;;;;;+3/p-3

InChI key

MIDYWIPTCYRMQF-UHFFFAOYSA-K

Features and Benefits

Used for the synthesis of bimetallic titanium(III) complexes with a triple-helix structure.

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Flam. Sol. 1 - Skin Corr. 1B

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Talukdar, S.; Banerji, A.
The Journal of Organic Chemistry, 63, 3468-3468 (1998)
Rele, S.; Talukdar, S.; Banerji, A.
Tetrahedron Letters, 40, 767-767 (1999)

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