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Sigma-Aldrich

Nickel(II) bromide ethylene glycol dimethyl ether complex

97%

Synonym(s):

(1,2-Dimethoxyethane)nickel dibromide, Dibromo(1,2-dimethoxyethane)nickel, Dibromo(1,2-dimethoxyethane)nickel(II)

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About This Item

Linear Formula:
NiBr2 · CH3OCH2CH2OCH3
CAS Number:
28923-39-9
Molecular Weight:
308.62
MDL number:
MFCD00013480
UNSPSC Code:
12352302
PubChem Substance ID:
24865368
NACRES:
NA.23

Assay

97%

form

powder

reaction suitability

reagent type: catalyst
core: nickel

SMILES string

Br[Ni]Br.COCCOC

InChI

1S/C4H10O2.2BrH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2

InChI key

VHSVJTYBTJCDFL-UHFFFAOYSA-L

Related Categories

General description

Nickel(II) bromide ethylene glycol dimethyl ether complex, also known as Ni(II) bromide ethylene glycol dimethyl ether complex. It is an organometallic coordination compound used as a precursor for the deposition of nickel-containing thin films. It is also found applications in organic synthesis as a Lewis acid catalyst.

Application

Nickel(II) bromide ethylene glycol dimethyl ether complex can be used as a precursor for synthesizing various nickel(II) complexes. These complexes used as a catalysts for:      
  • The selective transformation of ethylene into higher-order products.     
  • The vinyl polymerization of norbornene.      
  • The preparation of poly(3-hexylthiophene) (P3HT) Kumada catalyst transfer polymerization. It facilitates good control over the molecular weight of the conjugating polymer.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 Inhalation - Flam. Sol. 1 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1 Inhalation

Target Organs

Respiratory Tract,Skin

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

26.6 °F - Non-equilibrium method

Flash Point(C)

-3 °C - Non-equilibrium method

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Rapid flow-based synthesis of poly (3-hexylthiophene) using 2-methyltetrahydrofuran as a bio-derived reaction solvent
Bannock JH, et al.
European Polymer Journal, 80, 240-246 (2016)

Articles

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Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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