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Sigma-Aldrich

Hydrogen

≥99.99%

Synonym(s):

Hydrogen gas

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About This Item

Empirical Formula (Hill Notation):
H2
CAS Number:
Molecular Weight:
2.02
EC Number:
MDL number:
UNSPSC Code:
12142100
PubChem Substance ID:
NACRES:
NA.22

vapor density

0.07 (21 °C, vs air)

Quality Level

Assay

≥99.99%

autoignition temp.

1060 °F

expl. lim.

74.2 %

impurities

≤10 ppm oxygen
≤5 ppm water

bp

−252.8 °C (lit.)

mp

−259.2 °C (lit.)

SMILES string

[H]

InChI

1S/H2/h1H

InChI key

UFHFLCQGNIYNRP-UHFFFAOYSA-N

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General description

Hydrogen(H2) is colorless, odorless, tasteless, non-toxic, and highly flammable diatomic gas.

Application

H2 can be used:
  • To reduce metal oxide to metal.
  • In the catalytic hydrogenation of nitro compounds, ketones, and olefinic compounds.

Packaging

Supplied in a carbon steel lecture bottle with a CGA180M/CGA110F needle valve installed.

Compatible with the following:
  • Aldrich® lecture-bottle station systems
  • Aldrich® lecture-bottle gas regulators

Other Notes

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC

hose barb

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purge valve

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Pictograms

FlameGas cylinder

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Flam. Gas 1A - Press. Gas Compr. Gas

Storage Class Code

2A - Gases

WGK

nwg

Flash Point(F)

<-238.0 °F - closed cup

Flash Point(C)

< -150 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Metal-free catalytic olefin hydrogenation: low-temperature H2 activation by frustrated Lewis pairs
Greb L, et al.
Angewandte Chemie (International ed. in English), 51(40), 10164-10168 (2012)
Gold catalysts open a new general chemoselective route to synthesize oximes by hydrogenation of α, β,-unsaturated nitrocompounds with H2
Corma A, et al.
Journal of the American Chemical Society, 129(20), 6358-6359 (2007)
Catalytic reductive transformations of carboxylic and carbonic acid derivatives using molecular hydrogen
Dub, Pavel A and Ikariya, Takao
ACS Catalysis, 2(8), 1718-1741 (2012)
Effects of reduction temperature and metal- support interactions on the catalytic activity of Pt/γ-Al2O3 and Pt/TiO2 for the oxidation of CO in the presence and absence of H2
Alexeev OS, et al.
The Journal of Physical Chemistry B, 109(49), 23430-23443 (2005)
Patrick S Fier et al.
Science (New York, N.Y.), 342(6161), 956-960 (2013-11-23)
Fluorinated heterocycles are prevalent in pharmaceuticals, agrochemicals, and materials. However, reactions that incorporate fluorine into heteroarenes are limited in scope and can be hazardous. We present a broadly applicable and safe method for the site-selective fluorination of a single carbon-hydrogen

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