229180

(+)-Diisopropyl L-tartrate

98%, optical purity ee: 99% (GLC)

• Synonym(s): L-(+)-Tartaric acid diisopropyl ester
• Linear Formula: [-CH(OH)CO₂CH(CH₃)₂]₂
• CAS Number: 2217-15-4
• Molecular Weight: 234.25
• Beilstein: 1727863
• EC Number: 218-709-0
• MDL number: MFCD00064450
• UNSPSC Code: 12352108
• eCl@ss: 39021705
• PubChem Substance ID: 24853734
• NACRES: NA.22

Properties

• Assay: 98%
• form: liquid
• optical activity: [α]24/D +17°, neat
• optical purity: ee: 99% (GLC)
• refractive index: n20/D 1.439 (lit.)
• bp: 152 °C/12 mmHg (lit.)
• density: 1.114 g/mL at 25 °C (lit.)
• SMILES string: CC(C)OC(=O)[C@H](O)[C@@H](O)C(=O)OC(C)C
• InChI: 1S/C10H18O6/c1-5(2)15-9(13)7(11)8(12)10(14)16-6(3)4/h5-8,11-12H,1-4H3/t7-,8-/m1/s1
• InChI key: XEBCWEDRGPSHQH-HTQZYQBOSA-N

Description

Application

Both D- and L-forms are reagents for kinetic resolution of racemic allylic alcohols and α-furfuryl amides by enantioselective epoxidation.

Safety Information

• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves