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204668

Sigma-Aldrich

Thulium(III) chloride hexahydrate

99.99% trace metals basis

Synonym(s):

Thulium trichloride

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About This Item

Linear Formula:
TmCl3 · 6H2O
CAS Number:
1331-74-4
Molecular Weight:
383.38
EC Number:
236-904-9
MDL number:
MFCD00149878
UNSPSC Code:
12352302
PubChem Substance ID:
24852284
NACRES:
NA.23

Quality Level

100

Assay

99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: thulium

impurities

≤150.0 ppm Trace Rare Earth Analysis

SMILES string

O.O.O.O.O.O.Cl[Tm](Cl)Cl

InChI

1S/3ClH.6H2O.Tm/h3*1H;6*1H2;/q;;;;;;;;;+3/p-3

InChI key

XBIAQAHPMBNVJE-UHFFFAOYSA-K

General description

Thulium(III) chloride hexahydrate is white crystalline water- soluble salt. Owing to its ionic conductivity and stability, it is widely used in the field of solar cells and semiconductor applications.

Application

Thulium(III) chloride hexahydrate can be used:
  • As a precursor to prepare co-doped ZrO2 with enhanced optoelectronic feature like band gap and crystal sizes. These Tm doped metal oxides are used in supercapacitors and perovskite solar cells.
  • As Tm source to synthesize NaYF4:Yb,Tm upconversion nanocrystal-semiconductor hybrid structures with wide spectrum photocatalytic activity.
  • As a dopant to prepare LaCl3:Tm3+ single crystals for ,use in spectroscopic applications for radiation detection.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Facet engineered interface design of NaYF 4 :Yb,Tm upconversion nanocrystals on BiOCl nanoplates for enhanced near-infrared photocatalysis.
Bai L, et al.
Nanoscale, 8(45), 19014-19024 null
Libing Fu et al.
Nanoscale, 9(36), 13683-13692 (2017-09-07)
There is considerable interest in developing diagnostic nanotools for early detection and delivery of various therapeutic agents for treatment of neurodegenerative diseases. However, a key challenge remains in the selection of suitable surfaces to overcome the nano-bio interface issue, namely
Hongjun Zhuang et al.
Nanoscale, 12(18), 10216-10225 (2020-05-02)
Because of the low tissue penetration depth and poor photostability of organic cyanine dye, in addition to environmental interference, it is a great challenge to monitor the degree of drug-induced hepatotoxicity by the in vivo detection of peroxynitrite (ONOO-). Herein
Paulino Alonso-Cristobal et al.
ACS applied materials & interfaces, 7(27), 14992-14999 (2015-06-23)
Herein, we present a phototriggered drug delivery system based on light responsive nanoparticles, which is able to release doxorubicin upon NIR light illumination. The proposed system is based on upconversion fluorescence nanoparticles of β-NaYF4:Yb,Tm@SiO2-PEG with a mean diameter of 52±2.5

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