16467
(4-Bromobenzyl)trimethylsilane
≥97.0% (GC)
Synonym(s):
4-Bromo-α-(trimethylsilyl)toluene
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About This Item
Linear Formula:
BrC6H4CH20Si(CH3)3
CAS Number:
Molecular Weight:
243.22
Beilstein:
774733
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
≥97.0% (GC)
SMILES string
C[Si](C)(C)Cc1ccc(Br)cc1
InChI
1S/C10H15BrSi/c1-12(2,3)8-9-4-6-10(11)7-5-9/h4-7H,8H2,1-3H3
InChI key
YOBIYNREFRBEGA-UHFFFAOYSA-N
General description
(4-Bromobenzyl)trimethylsilane is the precursor for preparing a polymer bound fluoride labile benzhydryl linker.
Application
(4-Bromobenzyl)trimethylsilane was used as starting reagent during the synthesis of:
- 2-(4-bromophenyl)-1-(4-methoxyphenyl)ethanol
- (E)-1-(4-bromophenyl)-4-phenylbut-3-en-2-ol
- 1-(4-bromophenyl)-2-phenylpropan-2-ol
Other Notes
Precursor for preparing a polymer bound fluoride labile benzhydryl linker
Hazard Statements
Hazard Classifications
Aquatic Chronic 4
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Synthesis and application of benzyl-TMS derivatives as bench stable benzyl anion equivalents.
Das M and O'Shea DF.
Tetrahedron, 69(31), 6448-6460 (2013)
A. Routledge et al.
Tetrahedron Letters, 38, 8287-8287 (1997)
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