124109
1-Bromo-2-methylnaphthalene
technical grade, 90%
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£89.60
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£228.90
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25 G
£89.60
100 G
£228.90
About This Item
Linear Formula:
CH3C10H6Br
CAS Number:
Molecular Weight:
221.09
Beilstein:
2042531
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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grade
technical grade
Quality Level
Assay
90%
form
liquid
refractive index
n20/D 1.648 (lit.)
bp
296 °C (lit.)
density
1.418 g/mL at 25 °C (lit.)
functional group
bromo
SMILES string
Cc1ccc2ccccc2c1Br
InChI
1S/C11H9Br/c1-8-6-7-9-4-2-3-5-10(9)11(8)12/h2-7H,1H3
InChI key
CMIMBQIBIZZZHQ-UHFFFAOYSA-N
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General description
Dynamic phosphorescence quenching of 1-bromo-2-methylnaphthalene without deoxygenation has been used for selective sensing of Cu(II) at ngml-1 levels[1]. It undergoes asymmetric cross-coupling reaction with its corresponding Grignard reagent using a nickel catalyst to form non-racemic 2,2′-dimethyl-1,1′-binaphthyl[2].
Application
1-Bromo-2-methylnaphthalene was used as test compound in determination of halogenated hydrocarbons at trace levels by supercritical fluid chromatography-microwave-induced plasma mass spectrometry[3].
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
235.4 °F - closed cup
Flash Point(C)
113 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Determination of halogenated compounds with supercritical fluid chromatography-microwave-induced plasma mass spectrometry.
Olson LK and Caruso JA.
Journal of Analytical Atomic Spectrometry, 7(6), 993-998 (1992)
Synthesis of chiral binaphthalenes using the asymmetric Suzuki reaction.
Cammidge AN and Crepy KVL.
Tetrahedron, 60(20), 4377-4386 (2004)
N A Vinokurova
Voprosy onkologii, 21(3), 19-24 (1975-01-01)
The author presents an analysis of the results of the combination chemotherapy with natulan, vincristin, novembichine and prednisolone in 43 patients showing generalized lymphogranulomatosis, mainly with recurrences following radiation and chemotherapy with different antitumor substances. The results of the combination
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